The four structures having same physical properties like boiling point, melting point, density etc needs to be determined. Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Question

3- Draw the structural isomers for C5H10. Ignore any cyclic isomers. 4- How many isomers are there of "dichloroethene"? 5- How many structural and geometrical isomers are there of (chloropropene)?

Answer 1

Question

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

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3- Draw the structural isomers for C5H10. Ignore any cyclic isomers. 4- How many isomers are there of "dichloroethene"? 5- How many structural and geometrical isomers are there of (chloropropene)?

Answer both questions below: Draw the structural formulae of the stereo-isomers of the compound B What single physical property would you use to distinguish between pure samples of these isomers?

3. Draw all the isomers (including structural and geometric isomers) of CH;Br; which contain a carbon-carbon double bond.

Answer 2

Question

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

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Answer 3

Question

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

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Answer 4

Question

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

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Answer 5

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 6

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 7

Chapter 21, Problem 23E

(a)

Interpretation Introduction

Interpretation: The four structures having same physical properties like boiling point, melting point, density etc needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structure from the given four structures which are trans isomers needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as Configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 10

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation: The structures which do not possess cis-trans isomerism needs to be determined.

Concept Introduction : Cis-trans isomerism is also known as configurational or geometrical isomerism. The prefixes cis and trans are Latin words in which ‘‘cis’’ represents ‘‘this side of’’ and ‘‘trans’’ represents ‘‘the other side’’. This type of isomerism occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups in a molecule.

Answer 12

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Answer 23

Ch. 21 - Prob. 1E Ch. 21 - Prob. 2E Ch. 21 - Why are cyclopropane and cyclobutane so reactive?Ch. 21 - Prob. 4E Ch. 21 - Prob. 5E Ch. 21 - Prob. 6E Ch. 21 - Prob. 7E Ch. 21 - Name the five structural isomers of C6H14 .Ch. 21 - Draw the structural formula for each of the...Ch. 21 - Prob. 10E

Solution Summary: The author explains Cis-trans isomerism, which occurs in unsaturated compounds (i.e. double bonds) or cyclic compounds depending on the presence of substituted groups.

Chapter 21 Solutions