(a) Interpretation: Lewis acid and Lewis base are to be identified in the reaction of oxalate ion ( C 2 O 4 2 − ) with Fe 3 + which results in [Fe(C 2 O 4 ) 3 ] 3 − Concept introduction: The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.

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Answer 1

Question

Chapter 21, Problem 21.75SP

Interpretation Introduction

(a)

Interpretation:

Lewis acid and Lewis base are to be identified in the reaction of oxalate ion (C2O42−) with Fe3+ which results in [Fe(C2O4)3]3−

Concept introduction:

The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

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Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling point, choose 2 next to the substance with the next highest boiling point, and so on. substance C D chemical symbol, chemical formula or Lewis structure. CH,-N-CH, CH, H H 10: H C-C-H H H H Cale H 10: H-C-C-N-CH, Bri CH, boiling point (C) Сен (C) B (Choose

Answer 2

Question

Chapter 21, Problem 21.75SP

Interpretation Introduction

(a)

Interpretation:

Lewis acid and Lewis base are to be identified in the reaction of oxalate ion (C2O42−) with Fe3+ which results in [Fe(C2O4)3]3−

Concept introduction:

The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Expert Solution & Answer

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Answer 3

Question

Chapter 21, Problem 21.75SP

Interpretation Introduction

(a)

Interpretation:

Lewis acid and Lewis base are to be identified in the reaction of oxalate ion (C2O42−) with Fe3+ which results in [Fe(C2O4)3]3−

Concept introduction:

The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

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Answer 4

Question

Chapter 21, Problem 21.75SP

Interpretation Introduction

(a)

Interpretation:

Lewis acid and Lewis base are to be identified in the reaction of oxalate ion (C2O42−) with Fe3+ which results in [Fe(C2O4)3]3−

Concept introduction:

The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.75SP

Interpretation Introduction

(a)

Interpretation:

Lewis acid and Lewis base are to be identified in the reaction of oxalate ion (C2O42−) with Fe3+ which results in [Fe(C2O4)3]3−

Concept introduction:

The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Answer 6

Chapter 21, Problem 21.75SP

Interpretation Introduction

(a)

Interpretation:

Lewis acid and Lewis base are to be identified in the reaction of oxalate ion (C2O42−) with Fe3+ which results in [Fe(C2O4)3]3−

Concept introduction:

The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.

Answer 7

Chapter 21, Problem 21.75SP

Interpretation Introduction

(a)

Interpretation:

Lewis acid and Lewis base are to be identified in the reaction of oxalate ion (C2O42−) with Fe3+ which results in [Fe(C2O4)3]3−

Concept introduction:

The molecules which donate the electrons are known as Lewis base while the molecules which accepts the electrons are known as Lewis acid.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains that Lewis acid and Lewis base are to be identified in the reaction of oxalate ion with Fe3+.

Concept explainers

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(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

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Chapter 21 Solutions

Solution Summary: The author explains that Lewis acid and Lewis base are to be identified in the reaction of oxalate ion with Fe3+.

Concept explainers

Videos

(b) Interpretation: The ligands and donor atoms are to be identified. Concept introduction: Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

(c) Interpretation: The coordination number and geometry of the metal present in the complex are to be determined. Concept introduction: The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Want to see the full answer?

Chapter 21 Solutions

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.