(a) Interpretation: The structure of Pt(en) 2 complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex. Concept introduction: When considering transition metals , some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 1

Question

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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5. Draw molecular orbital diagrams for superoxide (O2¯), and peroxide (O2²-). A good starting point would be MO diagram for O2 given in your textbook. Then: a) calculate bond orders in superoxide and in peroxide; indicate which species would have a stronger oxygen-oxygen bond; b) indicate which species would be a radical. (4 points)

16. Which one of the compunds below is the final product of the reaction sequence shown here? عملاء .OH Br. (CH3)2CH-C=C H+,H,O 2 mol H2, Pt A OH B OH D OH E OH C OH

Indicate whether any of the two options is correct.a) The most common coordination structure for isopolianions is the prismb) Heteropolianions incorporate alkaline cations into their structures

Answer 2

Question

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 3

Question

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 4

Question

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 5

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 6

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 7

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains the structure of Pt(en) 2 complex and the oxidation state, coordination number and coordination geometry of the metal in the complex.

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Chapter 21 Solutions