(a) Interpretation: The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is 3.2 × 10 − 5 s − 1 at 25 ° C . Concept introduction: The following formula will be used − t 1/2 = 0 .693 k Here, k is rate constant.

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Answer 1

Question

Chapter 21, Problem 21.138MP

Interpretation Introduction

(a)

Interpretation:

The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is $3.2×10−5s−1$ at $25°C$ .

Concept introduction:

The following formula will be used −

$t1/2=0.693k$

Here, k is rate constant.

Interpretation Introduction

(b)

Interpretation:

The molarity after the 16.5 h of reaction time is to be determined, when the initial concentration of the trans- $[Co(en)2Cl2]+$ is 0.138M.

Concept introduction:

The following formula will be used −

$ln[A]t[A]0=−k.t$

Here, $[A]t$ is concentration of A at time t, $[A]0$ is initial concentration of A, k is rate constant and t is time.

Interpretation Introduction

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Interpretation Introduction

(d)

Interpretation:

Whether the reaction product is chiral or achiral needs to be determined.

Concept introduction:

The diastereomers are known as the achiral molecules which have non−mirror image and non-identical stereoisomer. While an enantiomer are known as chiral molecules which consist plane of symmetry and having mirror image and identical stereoisomer.

Interpretation Introduction

(e)

Interpretation:

The crystal field energy diagram of the trans- $[Co(en)2Cl2]+$ is to be drawn by considering that the $Cl−$ is weaker field ligand in comparison of the ethylenediamine.

Concept introduction:

There can be different versions of a different element in the nature these versions are called isotopes.

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Answer 2

Question

Chapter 21, Problem 21.138MP

Interpretation Introduction

(a)

Interpretation:

The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is $3.2×10−5s−1$ at $25°C$ .

Concept introduction:

The following formula will be used −

$t1/2=0.693k$

Here, k is rate constant.

Interpretation Introduction

(b)

Interpretation:

The molarity after the 16.5 h of reaction time is to be determined, when the initial concentration of the trans- $[Co(en)2Cl2]+$ is 0.138M.

Concept introduction:

The following formula will be used −

$ln[A]t[A]0=−k.t$

Here, $[A]t$ is concentration of A at time t, $[A]0$ is initial concentration of A, k is rate constant and t is time.

Interpretation Introduction

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Interpretation Introduction

(d)

Interpretation:

Whether the reaction product is chiral or achiral needs to be determined.

Concept introduction:

The diastereomers are known as the achiral molecules which have non−mirror image and non-identical stereoisomer. While an enantiomer are known as chiral molecules which consist plane of symmetry and having mirror image and identical stereoisomer.

Interpretation Introduction

(e)

Interpretation:

The crystal field energy diagram of the trans- $[Co(en)2Cl2]+$ is to be drawn by considering that the $Cl−$ is weaker field ligand in comparison of the ethylenediamine.

Concept introduction:

There can be different versions of a different element in the nature these versions are called isotopes.

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Answer 3

Question

Chapter 21, Problem 21.138MP

Interpretation Introduction

(a)

Interpretation:

The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is $3.2×10−5s−1$ at $25°C$ .

Concept introduction:

The following formula will be used −

$t1/2=0.693k$

Here, k is rate constant.

Interpretation Introduction

(b)

Interpretation:

The molarity after the 16.5 h of reaction time is to be determined, when the initial concentration of the trans- $[Co(en)2Cl2]+$ is 0.138M.

Concept introduction:

The following formula will be used −

$ln[A]t[A]0=−k.t$

Here, $[A]t$ is concentration of A at time t, $[A]0$ is initial concentration of A, k is rate constant and t is time.

Interpretation Introduction

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Interpretation Introduction

(d)

Interpretation:

Whether the reaction product is chiral or achiral needs to be determined.

Concept introduction:

The diastereomers are known as the achiral molecules which have non−mirror image and non-identical stereoisomer. While an enantiomer are known as chiral molecules which consist plane of symmetry and having mirror image and identical stereoisomer.

Interpretation Introduction

(e)

Interpretation:

The crystal field energy diagram of the trans- $[Co(en)2Cl2]+$ is to be drawn by considering that the $Cl−$ is weaker field ligand in comparison of the ethylenediamine.

Concept introduction:

There can be different versions of a different element in the nature these versions are called isotopes.

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Answer 4

Question

Chapter 21, Problem 21.138MP

Interpretation Introduction

(a)

Interpretation:

The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is $3.2×10−5s−1$ at $25°C$ .

Concept introduction:

The following formula will be used −

$t1/2=0.693k$

Here, k is rate constant.

Interpretation Introduction

(b)

Interpretation:

The molarity after the 16.5 h of reaction time is to be determined, when the initial concentration of the trans- $[Co(en)2Cl2]+$ is 0.138M.

Concept introduction:

The following formula will be used −

$ln[A]t[A]0=−k.t$

Here, $[A]t$ is concentration of A at time t, $[A]0$ is initial concentration of A, k is rate constant and t is time.

Interpretation Introduction

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Interpretation Introduction

(d)

Interpretation:

Whether the reaction product is chiral or achiral needs to be determined.

Concept introduction:

The diastereomers are known as the achiral molecules which have non−mirror image and non-identical stereoisomer. While an enantiomer are known as chiral molecules which consist plane of symmetry and having mirror image and identical stereoisomer.

Interpretation Introduction

(e)

Interpretation:

The crystal field energy diagram of the trans- $[Co(en)2Cl2]+$ is to be drawn by considering that the $Cl−$ is weaker field ligand in comparison of the ethylenediamine.

Concept introduction:

There can be different versions of a different element in the nature these versions are called isotopes.

Expert Solution & Answer

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See solution

Answer 5

Chapter 21, Problem 21.138MP

Interpretation Introduction

(a)

Interpretation:

The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is $3.2×10−5s−1$ at $25°C$ .

Concept introduction:

The following formula will be used −

$t1/2=0.693k$

Here, k is rate constant.

Interpretation Introduction

(b)

Interpretation:

The molarity after the 16.5 h of reaction time is to be determined, when the initial concentration of the trans- $[Co(en)2Cl2]+$ is 0.138M.

Concept introduction:

The following formula will be used −

$ln[A]t[A]0=−k.t$

Here, $[A]t$ is concentration of A at time t, $[A]0$ is initial concentration of A, k is rate constant and t is time.

Interpretation Introduction

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Interpretation Introduction

(d)

Interpretation:

Whether the reaction product is chiral or achiral needs to be determined.

Concept introduction:

The diastereomers are known as the achiral molecules which have non−mirror image and non-identical stereoisomer. While an enantiomer are known as chiral molecules which consist plane of symmetry and having mirror image and identical stereoisomer.

Interpretation Introduction

(e)

Interpretation:

The crystal field energy diagram of the trans- $[Co(en)2Cl2]+$ is to be drawn by considering that the $Cl−$ is weaker field ligand in comparison of the ethylenediamine.

Concept introduction:

There can be different versions of a different element in the nature these versions are called isotopes.

Answer 6

Chapter 21, Problem 21.138MP

Interpretation Introduction

(a)

Interpretation:

The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is $3.2×10−5s−1$ at $25°C$ .

Concept introduction:

The following formula will be used −

$t1/2=0.693k$

Here, k is rate constant.

Answer 7

Chapter 21, Problem 21.138MP

Interpretation Introduction

(a)

Interpretation:

The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is $3.2×10−5s−1$ at $25°C$ .

Concept introduction:

The following formula will be used −

$t1/2=0.693k$

Here, k is rate constant.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The molarity after the 16.5 h of reaction time is to be determined, when the initial concentration of the trans- $[Co(en)2Cl2]+$ is 0.138M.

Concept introduction:

The following formula will be used −

$ln[A]t[A]0=−k.t$

Here, $[A]t$ is concentration of A at time t, $[A]0$ is initial concentration of A, k is rate constant and t is time.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The molarity after the 16.5 h of reaction time is to be determined, when the initial concentration of the trans- $[Co(en)2Cl2]+$ is 0.138M.

Concept introduction:

The following formula will be used −

$ln[A]t[A]0=−k.t$

Here, $[A]t$ is concentration of A at time t, $[A]0$ is initial concentration of A, k is rate constant and t is time.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether the reaction product is chiral or achiral needs to be determined.

Concept introduction:

The diastereomers are known as the achiral molecules which have non−mirror image and non-identical stereoisomer. While an enantiomer are known as chiral molecules which consist plane of symmetry and having mirror image and identical stereoisomer.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether the reaction product is chiral or achiral needs to be determined.

Concept introduction:

The diastereomers are known as the achiral molecules which have non−mirror image and non-identical stereoisomer. While an enantiomer are known as chiral molecules which consist plane of symmetry and having mirror image and identical stereoisomer.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The crystal field energy diagram of the trans- $[Co(en)2Cl2]+$ is to be drawn by considering that the $Cl−$ is weaker field ligand in comparison of the ethylenediamine.

Concept introduction:

There can be different versions of a different element in the nature these versions are called isotopes.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The crystal field energy diagram of the trans- $[Co(en)2Cl2]+$ is to be drawn by considering that the $Cl−$ is weaker field ligand in comparison of the ethylenediamine.

Concept introduction:

There can be different versions of a different element in the nature these versions are called isotopes.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

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Answer 19

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

(a) Interpretation: The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is 3.2 × 10 − 5 s − 1 at 25 ° C . Concept introduction: The following formula will be used − t 1/2 = 0 .693 k Here, k is rate constant.

Solution Summary: The author explains that the half-life of the reaction in hours is determined where the order of reaction is first and the rate of constant is 3.2times 10-5s-1 at 25

Concept explainers

(a)

Interpretation:

The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is $3.2×10−5s−1$ at $25°C$ .

Concept introduction:

The following formula will be used −

$t1/2=0.693k$

Here, k is rate constant.

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Want to see the full answer?

Chapter 21 Solutions

(a) Interpretation: The half-life of the reaction in hours is to be determined where the order of reaction is first and the rate of constant is 3.2 × 10 − 5 s − 1 at 25 ° C . Concept introduction: The following formula will be used − t 1/2 = 0 .693 k Here, k is rate constant.

Solution Summary: The author explains that the half-life of the reaction in hours is determined where the order of reaction is first and the rate of constant is 3.2times 10-5s-1 at 25

Concept explainers

(c) Interpretation: The possible reaction mechanism with unimolecular rate determining step is to be determined. Concept introduction: The reaction mechanism can be defined as the step by step sequence of any elementary reaction.

Want to see the full answer?

Chapter 21 Solutions

(c)

Interpretation:

The possible reaction mechanism with unimolecular rate determining step is to be determined.

Concept introduction:

The reaction mechanism can be defined as the step by step sequence of any elementary reaction.