The crystal field d -orbital energy-level diagram of the given complex is to be drawn and the number of the unpaired electron in the given complex is to be determined. Concept introduction: The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory . The crystal field theory is explained that the splitting of orbital degeneracy in the complex due to the presence of strong field ligand. The splitting of orbital degeneracy will be different in a different structure of the complex with different coordination numbers.

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Answer 1

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.15P

Interpretation Introduction

Interpretation:

The crystal field d -orbital energy-level diagram of the given complex is to be drawn and the number of the unpaired electron in the given complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The crystal field theory is explained that the splitting of orbital degeneracy in the complex due to the presence of strong field ligand. The splitting of orbital degeneracy will be different in a different structure of the complex with different coordination numbers.

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1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)

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Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.15P

Interpretation Introduction

Interpretation:

The crystal field d -orbital energy-level diagram of the given complex is to be drawn and the number of the unpaired electron in the given complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The crystal field theory is explained that the splitting of orbital degeneracy in the complex due to the presence of strong field ligand. The splitting of orbital degeneracy will be different in a different structure of the complex with different coordination numbers.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.15P

Interpretation Introduction

Interpretation:

The crystal field d -orbital energy-level diagram of the given complex is to be drawn and the number of the unpaired electron in the given complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The crystal field theory is explained that the splitting of orbital degeneracy in the complex due to the presence of strong field ligand. The splitting of orbital degeneracy will be different in a different structure of the complex with different coordination numbers.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.15P

Interpretation Introduction