(a) Interpretation: The isomers need to be labeled as trans- and cis −. Concept introduction: In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

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Answer 1

Question

Chapter 21, Problem 21.33CP

Interpretation Introduction

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

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Draw structures corresponding to the following names and give IUPAC names for the following compounds: (8 Point) a) b) c) CH3 CH2CH3 CH3CHCH2CH2CH CH3 C=C H3C H H2C=C=CHCH3 d) CI e) (3E,5Z)-2,6-Dimethyl-1,3,5,7-octatetraene f) (Z)-4-bromo-3-methyl-3-penten-1-yne g) cis-1-Bromo-2-ethylcyclopentane h) (5R)-4,4,5-trichloro-3,3-dimethyldecane

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Review: Design a total total synthesis synthesis of the following compound using methyloxacyclopropane and any other necessary reagents.

Answer 2

Question

Chapter 21, Problem 21.33CP

Interpretation Introduction

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

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Answer 3

Question

Chapter 21, Problem 21.33CP

Interpretation Introduction

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

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Answer 4

Question

Chapter 21, Problem 21.33CP

Interpretation Introduction

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

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Answer 5

Chapter 21, Problem 21.33CP

Interpretation Introduction

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

Interpretation Introduction

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

Answer 6

Chapter 21, Problem 21.33CP

Interpretation Introduction

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Answer 7

Chapter 21, Problem 21.33CP

Interpretation Introduction

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

Answer 10

Interpretation Introduction

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

Answer 11

Interpretation Introduction

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

(a) Interpretation: The isomers need to be labeled as trans- and cis −. Concept introduction: In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Solution Summary: The author explains that the isomers need to be labeled as trans- and cis.

Concept explainers

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

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Chapter 21 Solutions

(a) Interpretation: The isomers need to be labeled as trans- and cis −. Concept introduction: In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

Solution Summary: The author explains that the isomers need to be labeled as trans- and cis.

Concept explainers

(a) Interpretation: The isomers need to be labeled as trans- and cis −. Concept introduction: In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

(b) Interpretation: The identical isomers or the different isomers are to be determined. Concept introduction: In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

(c) Interpretation: It is to be determined whether any isomer exists as enantiomers. Concept introduction: The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.

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Chapter 21 Solutions

(a)

Interpretation:

The isomers need to be labeled as trans- and cis −.

Concept introduction:

In trans-form, the ligands are present at corners across from each other and in cis-form ligands are present at the adjacent corner of the isomer.

(b)

Interpretation:

The identical isomers or the different isomers are to be determined.

Concept introduction:

In trans- form the ligands are present at corners across from each other and in cis- form ligands are present at the adjacent corner of the isomer.

(c)

Interpretation:

It is to be determined whether any isomer exists as enantiomers.

Concept introduction:

The enantiomers are known as chiral molecules which consist no plane of symmetry and have non-superimposable mirror image.