Organic Chemistry-Package(Custom)
Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 21, Problem 21.4P
Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given IUPAC name is to be stated.

Concept introduction: One should follow the given steps to derive the structure of an aldehyde from its IUPAC name. The first step is finding of longest parent chain that contains an aldehyde group. The second step is changing of -e ending of the parent alkane to the suffix -al. However, when an aldehyde (CHO) group is bonded to a ring then after naming of ring, the suffix -carbaldehyde is used. The third step is numbering of chain or ring by putting the CHO group at C1, and using the general rules of nomenclature.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given IUPAC name is to be stated.

Concept introduction: One should follow the given steps to derive the structure of an aldehyde from its IUPAC name. The first step is finding of longest parent chain that contains an aldehyde group. The second step is changing of -e ending of the parent alkane to the suffix -al. However, when an aldehyde (CHO) group is bonded to a ring then after naming of ring, the suffix -carbaldehyde is used. The third step is numbering of chain or ring by putting the CHO group at C1, and using the general rules of nomenclature.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given IUPAC name is to be stated.

Concept introduction: One should follow the given steps to derive the structure of an aldehyde from its IUPAC name. The first step is finding of longest parent chain that contains an aldehyde group. The second step is changing of -e ending of the parent alkane to the suffix -al. However, when an aldehyde (CHO) group is bonded to a ring then after naming of ring, the suffix -carbaldehyde is used. The third step is numbering of chain or ring by putting the CHO group at C1, and using the general rules of nomenclature.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given IUPAC name is to be stated.

Concept introduction: One should follow the given steps to derive the structure of an aldehyde from its IUPAC name. The first step is finding of longest parent chain that contains an aldehyde group. The second step is changing of -e ending of the parent alkane to the suffix -al. However, when an aldehyde (CHO) group is bonded to a ring then after naming of ring, the suffix -carbaldehyde is used. The third step is numbering of chain or ring by putting the CHO group at C1, and using the general rules of nomenclature.

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Chapter 21 Solutions

Organic Chemistry-Package(Custom)

Ch. 21 - Prob. 21.11PCh. 21 - Prob. 21.12PCh. 21 - Prob. 21.13PCh. 21 - Prob. 21.14PCh. 21 - Problem 21.15 Draw the product of each...Ch. 21 - Prob. 21.16PCh. 21 - Prob. 21.17PCh. 21 - Outline a synthesis of each Wittig reagent from...Ch. 21 - Draw the products including stereoisomers formed...Ch. 21 - Prob. 21.20PCh. 21 - Prob. 21.21PCh. 21 - Show two methods to synthesize each alkene: a...Ch. 21 - Problem 21.22 The product formed when reacts with...Ch. 21 - What 1 amine and carbonyl compound are needed to...Ch. 21 - Prob. 21.25PCh. 21 - Prob. 21.26PCh. 21 - Prob. 21.27PCh. 21 - Problem 21.28 Draw a stepwise mechanism for the...Ch. 21 - Problem 21.29 Draw the products of each...Ch. 21 - Problem 21.30 Label each compound as an acetal, a...Ch. 21 - Problem 21.31 Draw a stepwise mechanism for the...Ch. 21 - Problem 21.32 Draw the products of each...Ch. 21 - Problem 21.33 Safrole is a naturally occurring...Ch. 21 - Problem 21.35 How would you use a protecting group...Ch. 21 - Prob. 21.35PCh. 21 - Problem 21.37 Two naturally occurring compounds...Ch. 21 - Problem 21.38 Draw the products of each...Ch. 21 - Prob. 21.38PCh. 21 - Problem 21.40 (a) Give the IUPAC name for A and B....Ch. 21 - 21.41 Rank the following compounds in order of...Ch. 21 - Prob. 21.41PCh. 21 - Give the IUPAC name for each compound. a. d. g. b....Ch. 21 - Give the structure corresponding to each name. a....Ch. 21 - Including stereoisomers, draw the 11 aldehydes...Ch. 21 - Prob. 21.45PCh. 21 - Prob. 21.46PCh. 21 - What alkyl halide is needed to prepare each Wittig...Ch. 21 - 21.46 Draw the products of each reaction. a. e....Ch. 21 - Prob. 21.49PCh. 21 - Prob. 21.50PCh. 21 - Prob. 21.51PCh. 21 - Prob. 21.52PCh. 21 - Prob. 21.53PCh. 21 - Rank the following compounds in order of...Ch. 21 - Which compound forms the higher concentration of...Ch. 21 - Prob. 21.56PCh. 21 - What Wittig reagent and carbonyl compound are...Ch. 21 - Prob. 21.58PCh. 21 - What reagents are needed to convert each compound...Ch. 21 - What reagents are needed to convert each compound...Ch. 21 - Prob. 21.61PCh. 21 - Devise a synthesis of each alkene using a Wittig...Ch. 21 - Devise a synthesis of each compound from...Ch. 21 - Prob. 21.64PCh. 21 - Prob. 21.65PCh. 21 - Prob. 21.66PCh. 21 - Prob. 21.67PCh. 21 - Prob. 21.68PCh. 21 - Prob. 21.69PCh. 21 - 21.64 Draw a stepwise mechanism for the following...Ch. 21 - 21.65 Draw a stepwise mechanism f or the following...Ch. 21 - Prob. 21.72PCh. 21 - 21.67 Draw a stepwise mechanism for each...Ch. 21 - 21.68 Draw a stepwise mechanism for the following...Ch. 21 - Prob. 21.75PCh. 21 - Prob. 21.76PCh. 21 - Prob. 21.77PCh. 21 - Prob. 21.78PCh. 21 - Prob. 21.79PCh. 21 - 21.73 Although the carbonyl absorption of cyclic...Ch. 21 - 21.74 Use the and data to determine the...Ch. 21 - 21.75 A solution of acetone in ethanol in the...Ch. 21 - Compounds A and B have molecular formula ....Ch. 21 - 21.77 An unknown compound C of molecular formula ...Ch. 21 - 21.78 An unknown compound D exhibits a strong...Ch. 21 - Prob. 21.86PCh. 21 - -D-Glucose, a hemiacetal, can be converted to a...Ch. 21 - 21.81 Draw a stepwise mechanism for the following...Ch. 21 - Prob. 21.89PCh. 21 - Prob. 21.90PCh. 21 - Prob. 21.91PCh. 21 - 21.86 Draw stepwise mechanism for the following...
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