Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

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Answer 1

Textbook Question

Chapter 21, Problem 21.1P

Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

Chapter 21, Problem 21.1P, Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

Expert Solution & Answer

Interpretation Introduction

Interpretation: The given compounds are to be arranged in order of increasing reactivity towards nucleophilic attack.

Concept introduction: Both aldehydes and ketones undergo nucleophilic addition reaction. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound.

Answer to Problem 21.1P

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

Both aldehydes and ketones undergo nucleophilic addition reaction. In this reaction, the nucleophilic attack takes place at carbonyl carbon. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound. Thus, the arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 2

Figure 1

Conclusion

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is shown in Figure 1.

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• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak

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Answer 2

Textbook Question

Chapter 21, Problem 21.1P

Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

Chapter 21, Problem 21.1P, Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

Expert Solution & Answer

Interpretation Introduction

Interpretation: The given compounds are to be arranged in order of increasing reactivity towards nucleophilic attack.

Concept introduction: Both aldehydes and ketones undergo nucleophilic addition reaction. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound.

Answer to Problem 21.1P

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

Both aldehydes and ketones undergo nucleophilic addition reaction. In this reaction, the nucleophilic attack takes place at carbonyl carbon. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound. Thus, the arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 2

Figure 1

Conclusion

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is shown in Figure 1.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Textbook Question

Chapter 21, Problem 21.1P

Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

Chapter 21, Problem 21.1P, Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

Expert Solution & Answer

Interpretation Introduction

Interpretation: The given compounds are to be arranged in order of increasing reactivity towards nucleophilic attack.

Concept introduction: Both aldehydes and ketones undergo nucleophilic addition reaction. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound.

Answer to Problem 21.1P

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

Both aldehydes and ketones undergo nucleophilic addition reaction. In this reaction, the nucleophilic attack takes place at carbonyl carbon. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound. Thus, the arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 2

Figure 1

Conclusion

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is shown in Figure 1.

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Answer 4

Textbook Question

Chapter 21, Problem 21.1P

Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

Chapter 21, Problem 21.1P, Rank the following compounds in order of increasing reactivity towards nucleophilic attack.

Expert Solution & Answer

Interpretation Introduction

Interpretation: The given compounds are to be arranged in order of increasing reactivity towards nucleophilic attack.

Concept introduction: Both aldehydes and ketones undergo nucleophilic addition reaction. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound.

Answer to Problem 21.1P

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

Both aldehydes and ketones undergo nucleophilic addition reaction. In this reaction, the nucleophilic attack takes place at carbonyl carbon. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound. Thus, the arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 2

Figure 1

Conclusion

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is shown in Figure 1.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Textbook Question

Answer 6

Textbook Question

Answer 7

Expert Solution & Answer

Interpretation Introduction

Interpretation: The given compounds are to be arranged in order of increasing reactivity towards nucleophilic attack.

Concept introduction: Both aldehydes and ketones undergo nucleophilic addition reaction. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound.

Answer to Problem 21.1P

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

Both aldehydes and ketones undergo nucleophilic addition reaction. In this reaction, the nucleophilic attack takes place at carbonyl carbon. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound. Thus, the arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 2

Figure 1

Conclusion

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is shown in Figure 1.

Answer 8

Expert Solution & Answer

Interpretation Introduction

Interpretation: The given compounds are to be arranged in order of increasing reactivity towards nucleophilic attack.

Concept introduction: Both aldehydes and ketones undergo nucleophilic addition reaction. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound.

Answer to Problem 21.1P

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

Both aldehydes and ketones undergo nucleophilic addition reaction. In this reaction, the nucleophilic attack takes place at carbonyl carbon. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound. Thus, the arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 2

Figure 1

Conclusion

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is shown in Figure 1.

Answer 9

Expert Solution & Answer

Answer 10

Expert Solution & Answer

Answer 11

Interpretation Introduction

Interpretation: The given compounds are to be arranged in order of increasing reactivity towards nucleophilic attack.

Concept introduction: Both aldehydes and ketones undergo nucleophilic addition reaction. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound.

Answer 12

Answer to Problem 21.1P

The arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 1

Answer 13

Explanation of Solution

Both aldehydes and ketones undergo nucleophilic addition reaction. In this reaction, the nucleophilic attack takes place at carbonyl carbon. The relative reactivity of carbonyl group is inversely proportional to the number of R groups bonded to it. This means more is the number of R groups around the carbonyl carbon, less is the reactivity of that carbonyl compound. Thus, the arrangement of given compounds in the increasing reactivity towards nucleophilic attack is,

ORGANIC CHEMISTRY, Chapter 21, Problem 21.1P , additional homework tip 2

Figure 1