ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 20.3, Problem 3P
Interpretation Introduction

Interpretation:

The structural formula for an acylium ion intermediate is to be written. The structural features of acylium ion that make it a viable intermediate are to be stated.

Concept introduction:

Acylium ion or acyl cation is obtained when the removal of a halide ion takes place from a molecule of p-methoxybenzoyl chloride in the presence of Lewis acid as a catalyst.

The general structural formula of the acylium ion is RC+=O····.

Resonance structure is a blend of two or more Lewis structures. Resonance structures are represented by a double headed arrow between the structures.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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