ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 20.8, Problem 6P
Interpretation Introduction

Interpretation:

The structure of the product having molecular formula C5H12O3, that is formed in the reaction of pentane-1,2,5-triacetate with dilute sulfuric acid is to be written. The other organic compound that is formed in this reaction is to be determined.

Concept introduction:

The reaction in which the hydrolysis of an ester into alcohol and carboxylic acid takes place in the presence of an acid catalyst, such a reaction is commonly known as acid-catalyzed hydrolysis of an ester.

The hydrolysis of esters is catalyzed by either an acid or a base. Acidic hydrolysis is the reverse of esterification, and the ester is heated with a large excess of water containing a strong-acid catalyst.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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