ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 20, Problem 36P
Interpretation Introduction

Interpretation:

The synthesis of each of the given compounds by using ethanol and sodium or potassium cyanide as the sources of carbon atoms and any other necessary inorganic reagents is to be shown.

Concept introduction:

KMnO4 acts as an oxidizing agent. Oxidation of primary alcohols by KMnO4 results in the formation of carboxylic acids.

Reaction of carboxylic acids with thionyl chloride results in the formation of acid chlorides.

The full form of PCC is pyridiniumchlorochromate. It acts as a mild oxidizing agent.

It oxidizes primary alcohols into aldehyde and secondary alcohol into ketones.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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