ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 20.4, Problem 4P
Interpretation Introduction

Interpretation:

The major products obtained by the reactions of benzoyl chloride with the given compounds are to be determined.

Concept introduction:

The reaction of acyl chloride with carboxylic acid in the presence of pyridine results in the formation of acid anhydrides.

When acyl chloride reacts with alcohol and pyridine is used as a catalyst, it results in the formation of ester as the final product.

The reaction of acyl chloride with amines and ammonia in the presence of sodium hydroxide results in the formation of amides.

The reaction of acyl chloride with water results in the formation of carboxylic acid as the final product.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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