ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 20.2, Problem 2P
Interpretation Introduction

Interpretation:

An explanation for the fact that N,N-dimethylformamide shows three signals for its nonequivalent carbons in its 13C NMR spectrum is to be given.

Concept introduction:

Spectroscopy is a method used to identify the structure of the molecule. It is based on the interactions that occur between matter and EMR (electromagnetic radiations).

The 13C NMR spectroscopy identifies the number of carbon atoms present in a molecule. The value of chemical peaks for any carbon atom depends upon the chemical environment around that carbon atom.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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