EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Chapter 20.12, Problem 25P
Interpretation Introduction

Interpretation:

The products (in chair conformers formed), from the reaction of β- D-galactose with ethanol and HCl have to be drawn.

Concept Introduction:

Sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise, β sugar.  Hydroxyl group of α-sugar present on right side in Fischer projection is represented down in Haworth projection and at axial position in chair conformation.

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Draw the products formed when b-d-galactose reacts with ethanol and HCl. (Show all structures aschair conformers.)
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The tea leaves that contain the caffeine to be isolated are predominantly composed of cellulose, a natural and extremely abundant polymer of glucose. Look up the chair structure of B-D-glucose (B-D-glucopyranose, the monomer from which the cellulose polymer is composed). Draw this structure, draw the flipped chair, and indicate which conformer you think is more stable, if either. BRIEFLY explain your choice.

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EBK ORGANIC CHEMISTRY

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