GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 2, Problem 82P
Platinum is a precious metal used in a wide variety of products. Besides being used in fine jewelry, platinum is the catalyst found in the catalytic converters of automobile exhaust systems, and platinum-containing drugs like cisplatin are used to treat some lung and ovarian cancers. Answer the following questions about the element platinum.
a. What is its element symbol?
b. What group number and period are assigned to platinum?
c. What is its
d. Is platinum classified as a main group element, transition metal, or inner transition metal?
e. In what block does platinum reside?
f. What is unusual about the electronic configuration for platinum:
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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that
both of them
have a molecular ion peak at m/2 =128. However ketone
(A) has a fragment peak at m/2 = 99 and 72
while ketone (B) snowed a
fragment peak at m/2 = 113 and 58.
9) Propose the most plausible structures for both ketones
b) Explain how you arrived at your conclusion by drawing the
Structures of the distinguishing fragments for each ketone,
including their fragmentation mechanisms.
Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from
the compound in KBr pellet) and the mass spectrum as shown below.
The mass spectrum of compound Tesla showed strong mt peak at 71.
TRANSMITTANCE
LOD
Relative Intensity
100
MS-NW-1539
40
20
80
T
44
55
10
15
20
25
30
35
40
45
50
55
60
65
70
75
m/z
D
4000
3000
2000
1500
1000
500
HAVENUMBERI-11
Chapter 2 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 2.1 - Give the symbol for each element. a. calcium, a...Ch. 2.1 - Give the name corresponding to each element...Ch. 2.1 - Locate each element in the periodic table and...Ch. 2.1 - Prob. 2.4PCh. 2.1 - Identify the elements used ineach example of...Ch. 2.1 - Identify the elements in each chemical formula,...Ch. 2.1 - Prob. 2.6PCh. 2.1 - Prob. 2.2PPCh. 2.2 - Prob. 2.3PPCh. 2.2 - Prob. 2.4PP
Ch. 2.2 - For the given atom: (a) determine the number of...Ch. 2.2 - How many protons, neutrons, and electrons are...Ch. 2.2 - What is the mass number of an atom that contains...Ch. 2.3 - For each atom give the following information: [1]...Ch. 2.3 - Write an isotope symbol for the isotope of...Ch. 2.3 - Magnesium has three isotopes that contain 12, 13,...Ch. 2.3 - Prob. 2.9PPCh. 2.3 - Calculate the atomic weight of each element given...Ch. 2.4 - Prob. 2.9PCh. 2.4 - Label each macronutrient in Figure 2.2 in the...Ch. 2.4 - Identify the element fitting each description. an...Ch. 2.4 - Identify each highlighted element in the periodic...Ch. 2.5 - How many electrons are present in each shell,...Ch. 2.6 - What element has each electronic configuration? a....Ch. 2.6 - What element(s) in the first and second period fit...Ch. 2.6 - Draw an orbital diagram for each element; (a)...Ch. 2.6 - Give the electronic configuration for each element...Ch. 2.7 - Prob. 2.13PPCh. 2.7 - Determine the number of valence electrons and give...Ch. 2.7 - Give the electron-dot symbol for each element: (a)...Ch. 2.8 - Which element in each pair has the larger atomic...Ch. 2.8 - Prob. 2.16PCh. 2.8 - Prob. 2.17PPCh. 2.8 - (a) Which of the indicated atoms has the smaller...Ch. 2 - Identify the elements used in each example of...Ch. 2 - Write a chemical formula for each example of...Ch. 2 - Give the name of the elements in each group of...Ch. 2 - What element(s) are designated by each symbol or...Ch. 2 - Does each chemical formula represent an element or...Ch. 2 - Identify the elements in each chemical formula and...Ch. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - Give all of the terms that apply to each...Ch. 2 - Give all of the terms that apply to each...Ch. 2 - Give the following information about the atom...Ch. 2 - Give the following information about the atom...Ch. 2 - Prob. 29PCh. 2 - Prob. 30PCh. 2 - Prob. 31PCh. 2 - Consider the four atoms-L, M, N, and X- with the...Ch. 2 - Label each region on the periodic table. Noble...Ch. 2 - Identify each highlighted element in the periodic...Ch. 2 - Prob. 35PCh. 2 - Prob. 36PCh. 2 - Prob. 37PCh. 2 - Prob. 38PCh. 2 - Prob. 39PCh. 2 - Complete the followin table for the two most...Ch. 2 - How many protons, neutrons, and electrons are...Ch. 2 - Give the number of protons, neutrons, and...Ch. 2 - Write the element symbol that fits each...Ch. 2 - Write the element symbol that fits each...Ch. 2 - Calculate the atomic weight of silver, which has...Ch. 2 - Calculate the atomic weight of antimony, which has...Ch. 2 - Prob. 47PCh. 2 - What is the maximum number of electrons that can...Ch. 2 - Prob. 49PCh. 2 - Use an orbital diagram to write the electronic...Ch. 2 - Prob. 51PCh. 2 - For each element in Problem 2.50: (a) Write out...Ch. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Give the total number of electrons, the number of...Ch. 2 - Give the total number of electrons, the number of...Ch. 2 - Prob. 57PCh. 2 - Prob. 58PCh. 2 - Prob. 59PCh. 2 - Prob. 60PCh. 2 - Prob. 61PCh. 2 - Which of the following orbital diagrams are...Ch. 2 - Prob. 63PCh. 2 - Prob. 64PCh. 2 - Prob. 65PCh. 2 - Write an electron-dot symbol for each element: (a)...Ch. 2 - Prob. 67PCh. 2 - Prob. 68PCh. 2 - Prob. 69PCh. 2 - Prob. 70PCh. 2 - Prob. 71PCh. 2 - For each pair of elements in Problem 2.70, label...Ch. 2 - Rank the atoms in each group in order of...Ch. 2 - Prob. 74PCh. 2 - Prob. 75PCh. 2 - Prob. 76PCh. 2 - Prob. 77PCh. 2 - Prob. 78PCh. 2 - Prob. 79PCh. 2 - (a) What is the chemical formula for...Ch. 2 - Answer the following questions about the...Ch. 2 - Platinum is a precious metal used in a wide...Ch. 2 - Prob. 83PCh. 2 - Answer the following questions about the...Ch. 2 - Prob. 85CPCh. 2 - Prob. 86CP
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