GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Question
Chapter 2, Problem 77P
Interpretation Introduction
Interpretation:
The increasing order of the ionization energy for nitrogen, fluorine magnesium, sodium and phosphorus is to be stated.
Concept introduction:
The minimum amount of energy required to remove the electron from its outermost shell present in the gaseous or isolated state. The ionization energy decreases down the group and increases along the period.
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 2 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 2.1 - Give the symbol for each element. a. calcium, a...Ch. 2.1 - Give the name corresponding to each element...Ch. 2.1 - Locate each element in the periodic table and...Ch. 2.1 - Prob. 2.4PCh. 2.1 - Identify the elements used ineach example of...Ch. 2.1 - Identify the elements in each chemical formula,...Ch. 2.1 - Prob. 2.6PCh. 2.1 - Prob. 2.2PPCh. 2.2 - Prob. 2.3PPCh. 2.2 - Prob. 2.4PP
Ch. 2.2 - For the given atom: (a) determine the number of...Ch. 2.2 - How many protons, neutrons, and electrons are...Ch. 2.2 - What is the mass number of an atom that contains...Ch. 2.3 - For each atom give the following information: [1]...Ch. 2.3 - Write an isotope symbol for the isotope of...Ch. 2.3 - Magnesium has three isotopes that contain 12, 13,...Ch. 2.3 - Prob. 2.9PPCh. 2.3 - Calculate the atomic weight of each element given...Ch. 2.4 - Prob. 2.9PCh. 2.4 - Label each macronutrient in Figure 2.2 in the...Ch. 2.4 - Identify the element fitting each description. an...Ch. 2.4 - Identify each highlighted element in the periodic...Ch. 2.5 - How many electrons are present in each shell,...Ch. 2.6 - What element has each electronic configuration? a....Ch. 2.6 - What element(s) in the first and second period fit...Ch. 2.6 - Draw an orbital diagram for each element; (a)...Ch. 2.6 - Give the electronic configuration for each element...Ch. 2.7 - Prob. 2.13PPCh. 2.7 - Determine the number of valence electrons and give...Ch. 2.7 - Give the electron-dot symbol for each element: (a)...Ch. 2.8 - Which element in each pair has the larger atomic...Ch. 2.8 - Prob. 2.16PCh. 2.8 - Prob. 2.17PPCh. 2.8 - (a) Which of the indicated atoms has the smaller...Ch. 2 - Identify the elements used in each example of...Ch. 2 - Write a chemical formula for each example of...Ch. 2 - Give the name of the elements in each group of...Ch. 2 - What element(s) are designated by each symbol or...Ch. 2 - Does each chemical formula represent an element or...Ch. 2 - Identify the elements in each chemical formula and...Ch. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - Give all of the terms that apply to each...Ch. 2 - Give all of the terms that apply to each...Ch. 2 - Give the following information about the atom...Ch. 2 - Give the following information about the atom...Ch. 2 - Prob. 29PCh. 2 - Prob. 30PCh. 2 - Prob. 31PCh. 2 - Consider the four atoms-L, M, N, and X- with the...Ch. 2 - Label each region on the periodic table. Noble...Ch. 2 - Identify each highlighted element in the periodic...Ch. 2 - Prob. 35PCh. 2 - Prob. 36PCh. 2 - Prob. 37PCh. 2 - Prob. 38PCh. 2 - Prob. 39PCh. 2 - Complete the followin table for the two most...Ch. 2 - How many protons, neutrons, and electrons are...Ch. 2 - Give the number of protons, neutrons, and...Ch. 2 - Write the element symbol that fits each...Ch. 2 - Write the element symbol that fits each...Ch. 2 - Calculate the atomic weight of silver, which has...Ch. 2 - Calculate the atomic weight of antimony, which has...Ch. 2 - Prob. 47PCh. 2 - What is the maximum number of electrons that can...Ch. 2 - Prob. 49PCh. 2 - Use an orbital diagram to write the electronic...Ch. 2 - Prob. 51PCh. 2 - For each element in Problem 2.50: (a) Write out...Ch. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Give the total number of electrons, the number of...Ch. 2 - Give the total number of electrons, the number of...Ch. 2 - Prob. 57PCh. 2 - Prob. 58PCh. 2 - Prob. 59PCh. 2 - Prob. 60PCh. 2 - Prob. 61PCh. 2 - Which of the following orbital diagrams are...Ch. 2 - Prob. 63PCh. 2 - Prob. 64PCh. 2 - Prob. 65PCh. 2 - Write an electron-dot symbol for each element: (a)...Ch. 2 - Prob. 67PCh. 2 - Prob. 68PCh. 2 - Prob. 69PCh. 2 - Prob. 70PCh. 2 - Prob. 71PCh. 2 - For each pair of elements in Problem 2.70, label...Ch. 2 - Rank the atoms in each group in order of...Ch. 2 - Prob. 74PCh. 2 - Prob. 75PCh. 2 - Prob. 76PCh. 2 - Prob. 77PCh. 2 - Prob. 78PCh. 2 - Prob. 79PCh. 2 - (a) What is the chemical formula for...Ch. 2 - Answer the following questions about the...Ch. 2 - Platinum is a precious metal used in a wide...Ch. 2 - Prob. 83PCh. 2 - Answer the following questions about the...Ch. 2 - Prob. 85CPCh. 2 - Prob. 86CP
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