The energy associated with single H-H eclipsed interaction should be determined. Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below: For example, energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon. Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

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Answer 1

Question

Chapter 2, Problem 53P

(a)

Interpretation Introduction

Interpretation: The energy associated with single H-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example, energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

(b)

Interpretation Introduction

Interpretation: The energy associated with single CH3-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(c)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(d)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl gauche interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

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Answer 2

Question

Chapter 2, Problem 53P

(a)

Interpretation Introduction

Interpretation: The energy associated with single H-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example, energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

(b)

Interpretation Introduction

Interpretation: The energy associated with single CH3-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(c)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(d)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl gauche interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

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Answer 3

Question

Chapter 2, Problem 53P

(a)

Interpretation Introduction

Interpretation: The energy associated with single H-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example, energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

(b)

Interpretation Introduction

Interpretation: The energy associated with single CH3-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(c)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(d)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl gauche interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

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Answer 4

Question

Chapter 2, Problem 53P

(a)

Interpretation Introduction

Interpretation: The energy associated with single H-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example, energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

(b)

Interpretation Introduction

Interpretation: The energy associated with single CH3-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(c)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(d)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl gauche interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

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Answer 5

Chapter 2, Problem 53P

(a)

Interpretation Introduction

Interpretation: The energy associated with single H-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example, energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

(b)

Interpretation Introduction

Interpretation: The energy associated with single CH3-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(c)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

(d)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl gauche interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

Answer 6

Chapter 2, Problem 53P

(a)

Interpretation Introduction

Interpretation: The energy associated with single H-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example, energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

Answer 7

Chapter 2, Problem 53P

(a)

Interpretation Introduction

Interpretation: The energy associated with single H-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example, energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

Answer 8

(b)

Interpretation Introduction

Interpretation: The energy associated with single CH3-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Answer 9

(b)

Interpretation Introduction

Interpretation: The energy associated with single CH3-H eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Answer 10

(c)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Answer 11

(c)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl eclipsed interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Answer 12

(d)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl gauche interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

Answer 13

(d)

Interpretation Introduction

Interpretation: The energy associated with single methyl-methyl gauche interaction should be determined.

Concept introduction: Various interconvertible forms that result from rotation around the C–C bind in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the C–C as illustrated below:

For example energetics of rotation about the C–C bond for 2,3-dimethylbutane is similar to the potential energy diagram of butane except for the added methyl groups at second and third carbon.

Because of relatively more bulkiness in the system compared to butane, the energy differences between the anti and all other conformations will increase, with the greatest increase at 180 ° .

Answer 14

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Answer 25

Ch. 2.1 - Prob. 2.1E Ch. 2.1 - Prob. 2.2E Ch. 2.1 - Prob. 2.3E Ch. 2.1 - Prob. 2.5TIY Ch. 2.1 - Prob. 2.6E Ch. 2.1 - Prob. 2.7E Ch. 2.2 - Prob. 2.8E Ch. 2.3 - Prob. 2.9E Ch. 2.3 - Prob. 2.10E Ch. 2.3 - Prob. 2.11E

Solution Summary: The author explains that the energy associated with single H-H eclipsed interaction should be determined.

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Chapter 2 Solutions