Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 2.9, Problem 2.28TIY
Interpretation Introduction

Interpretation: The expected potential-energy diagram for the rotation about the Organic Chemistry: Structure and Function, Chapter 2.9, Problem 2.28TIY , additional homework tip  1bond in Organic Chemistry: Structure and Function, Chapter 2.9, Problem 2.28TIY , additional homework tip  2should be drawn along with Newman projections of each staggered and eclipsed conformation.

Concept introduction: Various interconvertible forms that results from rotation around the Organic Chemistry: Structure and Function, Chapter 2.9, Problem 2.28TIY , additional homework tip  3bond in ethane are termed as conformer. To depict such conformation Newman projections are written. These are obtained by conversion of hashed-wedged line structure simply when molecule is viewed in a plane along the Organic Chemistry: Structure and Function, Chapter 2.9, Problem 2.28TIY , additional homework tip  4as illustrated below:

  Organic Chemistry: Structure and Function, Chapter 2.9, Problem 2.28TIY , additional homework tip  5

Thus in Newman projection of simple ethane molecule the “front” Organic Chemistry: Structure and Function, Chapter 2.9, Problem 2.28TIY , additional homework tip  6is depicted as intersection of three bonds with three attachedOrganic Chemistry: Structure and Function, Chapter 2.9, Problem 2.28TIY , additional homework tip  7The other three bonds connect to the large circle corresponding to “back” carbon in Organic Chemistry: Structure and Function, Chapter 2.9, Problem 2.28TIY , additional homework tip  8bond.

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