Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 2, Problem 2.7NP
Interpretation Introduction

Interpretation:

The value of q, w, ΔU and ΔH needs to be determined for the process in which 2.25 mole of an ideal gas sample is expanded adiabatically at275 K from 5.50 m3 to 25.0 m3 volume.

Concept Introduction: In thermodynamics, a reversible process can be defined as the process which can be reversed to its original state.

Hence in reversible processes, both the system and surroundings are returned to their initial states. In general all reversible processes are ideal processes and cannot occur naturally.

On the contrary, an irreversible process cannot come back to its initial condition. All spontaneous processes in nature are irreversible processes.

In an adiabatic process the heat change is zero therefore the work done will be equal to the change in the internal energy.

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