Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 2, Problem 2.17NP
Interpretation Introduction

Interpretation: The temperature of the system after the establishment of the thermal equilibrium needs to be determined.

Concept Introduction: The change in internal energy is calculated as follows:

  ΔU=nCV.m(TfTi)=q+w

Here, n is number of moles, CV,m is molar heat at constant volume and T is temperature.

Also, q is heat transferred and w is work done.

The work done is represented as follows:

  w=PexternalΔV

Here, P is external pressure and ΔV is change in volume.

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