Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
expand_more
expand_more
format_list_bulleted
Question
Chapter 2, Problem 2.1CP
Interpretation Introduction
Interpretation:For the given system, whether the heat or work flow across the boundary between system and surroundings or not needs to be determined.
Concept Introduction:
An adiabatic procedure is one which takes place so vastly that no heat transfer takes placebetween the system, or within the system and surroundings.If the heat is added at constant volume the heat energy goes completely into increasing the internal kinetic energy of the substances.
Expert Solution & Answer
Answer to Problem 2.1CP
On the resistor work is done and this work is done within the surrounding. The liquid’s temperature is changed by 1 0C. Hence due to the variation in temperature between system and surroundings, the flow of heat takes place across the boundary between surrounding and system.
Explanation of Solution
Suppose there is an adiabatic system containing a heating water and coil against a constant atmospheric pressure P atm.
The temperature increases when electrical energy is introduced within the system. As per the law of
Here,
Adiabatic container is the system that means that no heat is exchanged from the system as well as its surroundings.
Hence,
On the resistor work is done and it is done within the surroundings.
The liquid’s temperature is changed by 1 0C. Hence due to the variation in temperature between system and surroundings, the flow of heat takes place across the boundary between surrounding and system.
Want to see more full solutions like this?
Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
Predict the organic products that form in the reaction below:
H.
H+
+
OH
H+
Y
Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the
products.
In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the
structures in any arrangement that you like, so long as they aren't touching.
Explanation
Check
Click and drag to start drawing a
structure.
G
X
C
© 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Access
+
111
Carbonyl Chem
Choosing reagants for a Wittig reaction
What would be the best choices for the missing reagents 1 and 3 in this synthesis?
1. PPh3
3
1
2
2. n-BuLi
• Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like.
Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is.
• Note: if one of your reagents needs to contain a halogen, use bromine.
Explanation
Check
Click and drag to start drawing a structure.
×
©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use
A student proposes the transformation below in one step of an organic synthesis. There may be one or more reactants missing from the left-hand side, but there
are no products missing from the right-hand side. There may also be catalysts, small inorganic reagents, and other important reaction conditions missing from
the arrow.
• Is the student's transformation possible? If not, check the box under the drawing area.
. If the student's transformation is possible, then complete the reaction by adding any missing reactants to the left-hand side, and adding required catalysts,
inorganic reagents, or other important reaction conditions above and below the arrow.
• You do not need to balance the reaction, but be sure every important organic reactant or product is shown.
+
T
X
O
O
лет-ле
HO
OH
HO
OH
This transformation can't be done in one step.
Chapter 2 Solutions
Physical Chemistry
Ch. 2 - Prob. 2.1CPCh. 2 - Prob. 2.2CPCh. 2 - Prob. 2.3CPCh. 2 - Prob. 2.4CPCh. 2 - Prob. 2.5CPCh. 2 - Prob. 2.6CPCh. 2 - Prob. 2.7CPCh. 2 - Prob. 2.8CPCh. 2 - Prob. 2.9CPCh. 2 - Prob. 2.10CP
Ch. 2 - Prob. 2.11CPCh. 2 - Prob. 2.12CPCh. 2 - Prob. 2.13CPCh. 2 - Prob. 2.14CPCh. 2 - Prob. 2.15CPCh. 2 - Prob. 2.16CPCh. 2 - Prob. 2.17CPCh. 2 - Prob. 2.18CPCh. 2 - Prob. 2.19CPCh. 2 - Prob. 2.20CPCh. 2 - Prob. 2.21CPCh. 2 - Prob. 2.22CPCh. 2 - Prob. 2.23CPCh. 2 - Prob. 2.24CPCh. 2 - Prob. 2.25CPCh. 2 - Prob. 2.26CPCh. 2 - Prob. 2.1NPCh. 2 - Prob. 2.2NPCh. 2 - Prob. 2.3NPCh. 2 - Prob. 2.4NPCh. 2 - Prob. 2.5NPCh. 2 - Prob. 2.6NPCh. 2 - Prob. 2.7NPCh. 2 - Prob. 2.8NPCh. 2 - Prob. 2.9NPCh. 2 - Prob. 2.10NPCh. 2 - Prob. 2.11NPCh. 2 - Prob. 2.12NPCh. 2 - Prob. 2.13NPCh. 2 - Prob. 2.14NPCh. 2 - Prob. 2.15NPCh. 2 - Prob. 2.16NPCh. 2 - Prob. 2.17NPCh. 2 - Prob. 2.18NPCh. 2 - Prob. 2.19NPCh. 2 - Prob. 2.20NPCh. 2 - Prob. 2.21NPCh. 2 - Prob. 2.22NPCh. 2 - Prob. 2.23NPCh. 2 - Prob. 2.24NPCh. 2 - Prob. 2.25NPCh. 2 - Prob. 2.26NPCh. 2 - Prob. 2.27NPCh. 2 - Prob. 2.28NPCh. 2 - Prob. 2.29NPCh. 2 - Prob. 2.30NPCh. 2 - Prob. 2.31NPCh. 2 - Prob. 2.32NPCh. 2 - Prob. 2.33NPCh. 2 - Prob. 2.34NPCh. 2 - Prob. 2.35NPCh. 2 - Prob. 2.36NPCh. 2 - Prob. 2.37NPCh. 2 - Prob. 2.38NPCh. 2 - Prob. 2.39NPCh. 2 - Prob. 2.40NPCh. 2 - Prob. 2.41NPCh. 2 - Prob. 2.42NPCh. 2 - Prob. 2.43NPCh. 2 - Prob. 2.44NP
Knowledge Booster
Similar questions
- Determine the structures of the missing organic molecules in the following reaction: X+H₂O H* H+ Y OH OH Note: Molecules that share the same letter have the exact same structure. In the drawing area below, draw the skeletal ("line") structures of the missing organic molecules X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. X Sarrow_forwardPredict the major products of this organic reaction. If there aren't any products, because nothing will happen, check the box under the drawing area instead. No reaction. HO. O :☐ + G Na O.H Click and drag to start drawing a structure. XS xs H₂Oarrow_forwardWhat are the angles a and b in the actual molecule of which this is a Lewis structure? H H C H- a -H b H Note for advanced students: give the ideal angles, and don't worry about small differences from the ideal groups may have slightly different sizes. a = b = 0 °arrow_forward
- What are the angles a and b in the actual molecule of which this is a Lewis structure? :0: HCOH a Note for advanced students: give the ideal angles, and don't worry about small differences from the ideal that might be caused by the fact that different electron groups may have slightly different sizes. a = 0 b=0° Sarrow_forwardDetermine the structures of the missing organic molecules in the following reaction: + H₂O +H OH O OH +H OH X Note: Molecules that share the same letter have the exact same structure. In the drawing area below, draw the skeletal ("line") structure of the missing organic molecule X. Click and drag to start drawing a structure.arrow_forwardIdentify the missing organic reactant in the following reaction: x + x O OH H* + ☑- X H+ O O Х Note: This chemical equation only focuses on the important organic molecules in the reaction. Additional inorganic or small-molecule reactants or products (like H₂O) are not shown. In the drawing area below, draw the skeletal ("line") structure of the missing organic reactant X. Click and drag to start drawing a structure. Carrow_forward
- CH3O OH OH O hemiacetal O acetal O neither O 0 O hemiacetal acetal neither OH hemiacetal O acetal O neither CH2 O-CH2-CH3 CH3-C-OH O hemiacetal O acetal CH3-CH2-CH2-0-c-O-CH2-CH2-CH3 O neither HO-CH2 ? 000 Ar Barrow_forwardWhat would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 2 2. n-BuLi 3 Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure.arrow_forwardPredict the products of this organic reaction: NaBH3CN + NH2 ? H+ Click and drag to start drawing a structure. ×arrow_forward
- Predict the organic products that form in the reaction below: + OH +H H+ ➤ ☑ X - Y Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the products. In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. Garrow_forwardPredict the organic products that form in the reaction below: OH H+ H+ + ☑ Y Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the products. In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. ✓ marrow_forwardDetermine the structures of the missing organic molecules in the following reaction: + H₂O +H H+ Y Z ☑ ☑ Note: Molecules that share the same letter have the exact same structure. In the drawing area below, draw the skeletal ("line") structures of the missing organic molecules X, Y, and Z. You may draw the structures in any arrangement that you like, so long as they aren't touching. Molecule X shows up in multiple steps, but you only have to draw its structure once. Click and drag to start drawing a structure. AP +arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY