Chemistry for Engineering Students
Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
Question
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Chapter 2, Problem 2.62PAE

(a)

Interpretation Introduction

To determine:

The formula of sulfur dichloride.

(b)

Interpretation Introduction

To determine:

(c)

Interpretation Introduction

To determine:

(d)

Interpretation Introduction

To determine:

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Q2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol‍¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)! Google
Print Last Name, First Name Initial Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 4th total • 6H total 래 • 4H total 21 total ZH 2H Statistical H < 3° C-H weakest - product abstraction here bund leads to thermo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Product 6 Number of Unique Mono-Chlorinated Products Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary H H-Cl Waterfox

Chapter 2 Solutions

Chemistry for Engineering Students

Ch. 2 - Prob. 2.1PAECh. 2 - How do polymers compare to their respective...Ch. 2 - Look around you and identify several objects that...Ch. 2 - Prob. 2.4PAECh. 2 - The fact that a polymer’s physical properties...Ch. 2 - One application of conductive polymers is in...Ch. 2 - Prob. 2.7PAECh. 2 - Prob. 2.8PAECh. 2 - Why is the number of protons called the atomic...Ch. 2 - 2.10 Which isotope in each pair contains more...Ch. 2 - 2.11 Define the term isotope.Ch. 2 - 2.12 Write the complete atomic symbol for each of...Ch. 2 - 2.13 How many electrons, protons, and neutrons are...Ch. 2 - 2.14 Consider the following nuclear symbols. How...Ch. 2 - 2.15 Mercury is 16.716 times more massive than...Ch. 2 - The element gallium, used in gallium arsenide...Ch. 2 - 2.17 The atomic weight of copper is 63.55 amu....Ch. 2 - The following table presents the abundances and...Ch. 2 - 2.19 Naturally occurring uranium consists of two...Ch. 2 - Prob. 2.20PAECh. 2 - Prob. 2.21PAECh. 2 - 2.22 Provide the symbol of the following...Ch. 2 - Prob. 2.23PAECh. 2 - 2.24 Identify each of the following species as an...Ch. 2 - 2.25 Write the atomic symbol for the element whose...Ch. 2 - 2.26 In what region of the periodic table are you...Ch. 2 - Prob. 2.27PAECh. 2 - Prob. 2.28PAECh. 2 - Prob. 2.29PAECh. 2 - 2.30 Using Coulomb’s law, explain how the...Ch. 2 - Prob. 2.31PAECh. 2 - 2.32 Which of the following formulas contains the...Ch. 2 - Prob. 2.33PAECh. 2 - Prob. 2.34PAECh. 2 - Prob. 2.35PAECh. 2 - 2.36 Explain the difference between a molecular...Ch. 2 - 2.37 Why are empirical formulas preferred for...Ch. 2 - 2.38 The molecular formula for the ethylene...Ch. 2 - 239 Polybutadiene is a synthetic elastomer, or...Ch. 2 - 2.40 What distinguished the work of Mendeleev that...Ch. 2 - 2.41 How does the periodic table help to make the...Ch. 2 - 2.42 What is a period in the periodic table? From...Ch. 2 - 2.43 Name of the group to which each of the...Ch. 2 - Prob. 2.44PAECh. 2 - Prob. 2.45PAECh. 2 - 2.46 Why are nonmetals important even though they...Ch. 2 - Prob. 2.47PAECh. 2 - A materials engineer has filed for a patent for a...Ch. 2 - Prob. 2.49PAECh. 2 - 2.50 A materials engineer wants to make a new...Ch. 2 - Prob. 2.51PAECh. 2 - Prob. 2.52PAECh. 2 - 2.53 What is meant by the phrase organic...Ch. 2 - 2.54 Based on what you have learned in this...Ch. 2 - 2.55 What is a functional group? How does the...Ch. 2 - Prob. 2.56PAECh. 2 - Prob. 2.57PAECh. 2 - Prob. 2.58PAECh. 2 - 2.59 The accompanying figure shows the structure...Ch. 2 - Prob. 2.60PAECh. 2 - 2.61 Name the following covalent compounds: (a)...Ch. 2 - Prob. 2.62PAECh. 2 - Prob. 2.63PAECh. 2 - Prob. 2.64PAECh. 2 - Prob. 2.65PAECh. 2 - Prob. 2.66PAECh. 2 - Prob. 2.67PAECh. 2 - 2.68 What is a free radical? How are free radicals...Ch. 2 - Prob. 2.69PAECh. 2 - 2.70 Why do you think an inhibitor molecule is...Ch. 2 - 2.71 Use the web to determine the amount of...Ch. 2 - 2.72 How can an element have an atomic weight that...Ch. 2 - 2.73 Explain the concept of a “weighted” average...Ch. 2 - 2.74 The accompanying table provides the identity...Ch. 2 - 2.75 Chlorine has only two isotopes, one with mass...Ch. 2 - Prob. 2.76PAECh. 2 - Prob. 2.77PAECh. 2 - Prob. 2.78PAECh. 2 - Prob. 2.79PAECh. 2 - 2.80 Of the following elements, which two would...Ch. 2 - 2.81 How do binary compounds with hydrogen...Ch. 2 - Prob. 2.82PAECh. 2 - Prob. 2.83PAECh. 2 - 2.84 Early attempts to arrange the elements often...Ch. 2 - 2.85 Describe how the saying “opposites attract”...Ch. 2 - 2.86 For some uses, the relative abundance of...Ch. 2 - 2.87 What is the heaviest element to have an...Ch. 2 - 2.88 Describe how you can identify the isotope, X,...Ch. 2 - Prob. 2.89PAECh. 2 - 2.90 Naturally occurring europium has an average...Ch. 2 - 2.91 Strontium has four stable isotopes....Ch. 2 - 2.92 A candy manufacturer makes chocolate-covered...Ch. 2 - Prob. 2.93PAECh. 2 - 2.94 Use a molecular level description to...Ch. 2 - 2.95 Engineers who design bicycle frames are...Ch. 2 - 2.96 Use the web to look up the density of...Ch. 2 - 2.97 LDPE has a density in the range of...
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