The potential hydrogen bond donors and accepters present in Fig.1. Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or an atom.

Question

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Answer 1

Question

Chapter 2, Problem 1E

(a)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.1.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or an atom.

(a)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1, H₂N at the C2 position, and HN9. The potential hydrogen bond accepter groups are O at the C6 position, N3, and N7.

Explanation of Solution

Pictorial presentation: Fig. 1 shows structure of guanine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 1

Fig.1: Guanine

The given formula of Fig.1 is identified as Guanine. Here, at the HN1 position, the hydrogen bond is donated and nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen accepter. Therefore, at HN1, H2N at the C2 position, and HN9 portion, the hydrogen bond acts like a donor; O at the C6 position, N3, and N7 portion, the hydrogen bond acts like an acceptor.

(b)

Summary Introduction

To identify: The potential hydrogen bond donors and acceptors present in Fig.2.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(b)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1 and H₂N at the C4 position. The potential hydrogen bond accepter groups are O at the C2 position, N3.

Explanation of Solution

Pictorial presentation: Fig.2 shows structure of cytosine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 2

Fig.1: Cytosine

The given formula of Fig.2 is identified as cytosine. Here, at HN1 position, the hydrogen bond is donated as nitrogen acts as the hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at HN1 and H2N at the C4 position, the hydrogen bond acts like a donor and O at the C2 position and N3 portion, the hydrogen bond acts like an acceptor.

(c)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.3.

Concept introduction: Hydrogen bonds are formed between the polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(c)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are H₃N⁺ group and OH group. The potential hydrogen bond accepter groups are COO and OH.

Explanation of Solution

Pictorial presentation: Fig.3 shows structure of serine, where the potential hydrogen bond donors and acceptors are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 3

Fig.3: Serine

The given formula of Fig.3 is identified as serine. Here, at H₃N⁺ position, the hydrogen bond is donated as nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at H₃N⁺ group and OH group, the hydrogen bond acts like a donor and COO and OH position, the hydrogen bond acts like an acceptor.

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Students have asked these similar questions

The beta-lactamase hydrolyzes the lactam-ring in penicillin. Describe the mechanism of hydrolysis, insuring to include the involvement of S, D, & K in the reaction sequence. Please help

To map the active site of beta-lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine. Why doesn't D in this hexapeptide not participate in the hydrolysis of the beta-lactam ring even though S, K, and D are involved in the catalyst?

To map the active site of -lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine. Using the experimental results described above derive the primary sequence of the active site hexapeptide. Please help!

Answer 2

Question

Chapter 2, Problem 1E

(a)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.1.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or an atom.

(a)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1, H₂N at the C2 position, and HN9. The potential hydrogen bond accepter groups are O at the C6 position, N3, and N7.

Explanation of Solution

Pictorial presentation: Fig. 1 shows structure of guanine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 1

Fig.1: Guanine

The given formula of Fig.1 is identified as Guanine. Here, at the HN1 position, the hydrogen bond is donated and nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen accepter. Therefore, at HN1, H2N at the C2 position, and HN9 portion, the hydrogen bond acts like a donor; O at the C6 position, N3, and N7 portion, the hydrogen bond acts like an acceptor.

(b)

Summary Introduction

To identify: The potential hydrogen bond donors and acceptors present in Fig.2.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(b)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1 and H₂N at the C4 position. The potential hydrogen bond accepter groups are O at the C2 position, N3.

Explanation of Solution

Pictorial presentation: Fig.2 shows structure of cytosine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 2

Fig.1: Cytosine

The given formula of Fig.2 is identified as cytosine. Here, at HN1 position, the hydrogen bond is donated as nitrogen acts as the hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at HN1 and H2N at the C4 position, the hydrogen bond acts like a donor and O at the C2 position and N3 portion, the hydrogen bond acts like an acceptor.

(c)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.3.

Concept introduction: Hydrogen bonds are formed between the polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(c)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are H₃N⁺ group and OH group. The potential hydrogen bond accepter groups are COO and OH.

Explanation of Solution

Pictorial presentation: Fig.3 shows structure of serine, where the potential hydrogen bond donors and acceptors are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 3

Fig.3: Serine

The given formula of Fig.3 is identified as serine. Here, at H₃N⁺ position, the hydrogen bond is donated as nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at H₃N⁺ group and OH group, the hydrogen bond acts like a donor and COO and OH position, the hydrogen bond acts like an acceptor.

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Answer 3

Question

Chapter 2, Problem 1E

(a)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.1.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or an atom.

(a)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1, H₂N at the C2 position, and HN9. The potential hydrogen bond accepter groups are O at the C6 position, N3, and N7.

Explanation of Solution

Pictorial presentation: Fig. 1 shows structure of guanine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 1

Fig.1: Guanine

The given formula of Fig.1 is identified as Guanine. Here, at the HN1 position, the hydrogen bond is donated and nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen accepter. Therefore, at HN1, H2N at the C2 position, and HN9 portion, the hydrogen bond acts like a donor; O at the C6 position, N3, and N7 portion, the hydrogen bond acts like an acceptor.

(b)

Summary Introduction

To identify: The potential hydrogen bond donors and acceptors present in Fig.2.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(b)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1 and H₂N at the C4 position. The potential hydrogen bond accepter groups are O at the C2 position, N3.

Explanation of Solution

Pictorial presentation: Fig.2 shows structure of cytosine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 2

Fig.1: Cytosine

The given formula of Fig.2 is identified as cytosine. Here, at HN1 position, the hydrogen bond is donated as nitrogen acts as the hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at HN1 and H2N at the C4 position, the hydrogen bond acts like a donor and O at the C2 position and N3 portion, the hydrogen bond acts like an acceptor.

(c)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.3.

Concept introduction: Hydrogen bonds are formed between the polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(c)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are H₃N⁺ group and OH group. The potential hydrogen bond accepter groups are COO and OH.

Explanation of Solution

Pictorial presentation: Fig.3 shows structure of serine, where the potential hydrogen bond donors and acceptors are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 3

Fig.3: Serine

The given formula of Fig.3 is identified as serine. Here, at H₃N⁺ position, the hydrogen bond is donated as nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at H₃N⁺ group and OH group, the hydrogen bond acts like a donor and COO and OH position, the hydrogen bond acts like an acceptor.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Chapter 2, Problem 1E

(a)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.1.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or an atom.

(a)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1, H₂N at the C2 position, and HN9. The potential hydrogen bond accepter groups are O at the C6 position, N3, and N7.

Explanation of Solution

Pictorial presentation: Fig. 1 shows structure of guanine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 1

Fig.1: Guanine

The given formula of Fig.1 is identified as Guanine. Here, at the HN1 position, the hydrogen bond is donated and nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen accepter. Therefore, at HN1, H2N at the C2 position, and HN9 portion, the hydrogen bond acts like a donor; O at the C6 position, N3, and N7 portion, the hydrogen bond acts like an acceptor.

(b)

Summary Introduction

To identify: The potential hydrogen bond donors and acceptors present in Fig.2.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(b)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1 and H₂N at the C4 position. The potential hydrogen bond accepter groups are O at the C2 position, N3.

Explanation of Solution

Pictorial presentation: Fig.2 shows structure of cytosine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 2

Fig.1: Cytosine

The given formula of Fig.2 is identified as cytosine. Here, at HN1 position, the hydrogen bond is donated as nitrogen acts as the hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at HN1 and H2N at the C4 position, the hydrogen bond acts like a donor and O at the C2 position and N3 portion, the hydrogen bond acts like an acceptor.

(c)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.3.

Concept introduction: Hydrogen bonds are formed between the polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(c)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are H₃N⁺ group and OH group. The potential hydrogen bond accepter groups are COO and OH.

Explanation of Solution

Pictorial presentation: Fig.3 shows structure of serine, where the potential hydrogen bond donors and acceptors are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 3

Fig.3: Serine

The given formula of Fig.3 is identified as serine. Here, at H₃N⁺ position, the hydrogen bond is donated as nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at H₃N⁺ group and OH group, the hydrogen bond acts like a donor and COO and OH position, the hydrogen bond acts like an acceptor.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 2, Problem 1E

(a)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.1.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or an atom.

(a)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1, H₂N at the C2 position, and HN9. The potential hydrogen bond accepter groups are O at the C6 position, N3, and N7.

Explanation of Solution

Pictorial presentation: Fig. 1 shows structure of guanine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 1

Fig.1: Guanine

The given formula of Fig.1 is identified as Guanine. Here, at the HN1 position, the hydrogen bond is donated and nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen accepter. Therefore, at HN1, H2N at the C2 position, and HN9 portion, the hydrogen bond acts like a donor; O at the C6 position, N3, and N7 portion, the hydrogen bond acts like an acceptor.

(b)

Summary Introduction

To identify: The potential hydrogen bond donors and acceptors present in Fig.2.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(b)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1 and H₂N at the C4 position. The potential hydrogen bond accepter groups are O at the C2 position, N3.

Explanation of Solution

Pictorial presentation: Fig.2 shows structure of cytosine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 2

Fig.1: Cytosine

The given formula of Fig.2 is identified as cytosine. Here, at HN1 position, the hydrogen bond is donated as nitrogen acts as the hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at HN1 and H2N at the C4 position, the hydrogen bond acts like a donor and O at the C2 position and N3 portion, the hydrogen bond acts like an acceptor.

(c)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.3.

Concept introduction: Hydrogen bonds are formed between the polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(c)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are H₃N⁺ group and OH group. The potential hydrogen bond accepter groups are COO and OH.

Explanation of Solution

Pictorial presentation: Fig.3 shows structure of serine, where the potential hydrogen bond donors and acceptors are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 3

Fig.3: Serine

The given formula of Fig.3 is identified as serine. Here, at H₃N⁺ position, the hydrogen bond is donated as nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at H₃N⁺ group and OH group, the hydrogen bond acts like a donor and COO and OH position, the hydrogen bond acts like an acceptor.

Answer 6

Chapter 2, Problem 1E

(a)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.1.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or an atom.

(a)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1, H₂N at the C2 position, and HN9. The potential hydrogen bond accepter groups are O at the C6 position, N3, and N7.

Explanation of Solution

Pictorial presentation: Fig. 1 shows structure of guanine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 1

Fig.1: Guanine

The given formula of Fig.1 is identified as Guanine. Here, at the HN1 position, the hydrogen bond is donated and nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen accepter. Therefore, at HN1, H2N at the C2 position, and HN9 portion, the hydrogen bond acts like a donor; O at the C6 position, N3, and N7 portion, the hydrogen bond acts like an acceptor.

Answer 7

Chapter 2, Problem 1E

(a)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.1.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or an atom.

Answer 8

(a)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1, H₂N at the C2 position, and HN9. The potential hydrogen bond accepter groups are O at the C6 position, N3, and N7.

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

Pictorial presentation: Fig. 1 shows structure of guanine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 1

Fig.1: Guanine

The given formula of Fig.1 is identified as Guanine. Here, at the HN1 position, the hydrogen bond is donated and nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen accepter. Therefore, at HN1, H2N at the C2 position, and HN9 portion, the hydrogen bond acts like a donor; O at the C6 position, N3, and N7 portion, the hydrogen bond acts like an acceptor.

Answer 13

(b)

Summary Introduction

To identify: The potential hydrogen bond donors and acceptors present in Fig.2.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(b)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1 and H₂N at the C4 position. The potential hydrogen bond accepter groups are O at the C2 position, N3.

Explanation of Solution

Pictorial presentation: Fig.2 shows structure of cytosine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 2

Fig.1: Cytosine

The given formula of Fig.2 is identified as cytosine. Here, at HN1 position, the hydrogen bond is donated as nitrogen acts as the hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at HN1 and H2N at the C4 position, the hydrogen bond acts like a donor and O at the C2 position and N3 portion, the hydrogen bond acts like an acceptor.

Answer 14

(b)

Summary Introduction

To identify: The potential hydrogen bond donors and acceptors present in Fig.2.

Concept introduction: Hydrogen bonds are formed between polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

Answer 15

(b)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are HN1 and H₂N at the C4 position. The potential hydrogen bond accepter groups are O at the C2 position, N3.

Answer 16

(b)

Expert Solution

Answer 17

(b)

Expert Solution

Answer 18

Expert Solution

Answer 19

Explanation of Solution

Pictorial presentation: Fig.2 shows structure of cytosine, where the potential hydrogen bond donors and accepters are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 2

Fig.1: Cytosine

The given formula of Fig.2 is identified as cytosine. Here, at HN1 position, the hydrogen bond is donated as nitrogen acts as the hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at HN1 and H2N at the C4 position, the hydrogen bond acts like a donor and O at the C2 position and N3 portion, the hydrogen bond acts like an acceptor.

Answer 20

(c)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.3.

Concept introduction: Hydrogen bonds are formed between the polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

(c)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are H₃N⁺ group and OH group. The potential hydrogen bond accepter groups are COO and OH.

Explanation of Solution

Pictorial presentation: Fig.3 shows structure of serine, where the potential hydrogen bond donors and acceptors are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 3

Fig.3: Serine

The given formula of Fig.3 is identified as serine. Here, at H₃N⁺ position, the hydrogen bond is donated as nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at H₃N⁺ group and OH group, the hydrogen bond acts like a donor and COO and OH position, the hydrogen bond acts like an acceptor.

Answer 21

(c)

Summary Introduction

To identify: The potential hydrogen bond donors and accepters present in Fig.3.

Concept introduction: Hydrogen bonds are formed between the polar molecules. It is an intermolecular attraction that forms between partially positive hydrogen atoms of a polar molecule with a partially negative atom of another polar molecule. In general chemical formulation, a hydrogen bond is explained as D–H···A, where D–H is a hydrogen bond “donor group” and A is considered as a hydrogen bond accepter group or atom.

Answer 22

(c)

Expert Solution

Answer to Problem 1E

Correct answer: The potential hydrogen bond donor groups are H₃N⁺ group and OH group. The potential hydrogen bond accepter groups are COO and OH.

Answer 23

(c)

Expert Solution

Answer 24

(c)

Expert Solution

Answer 25

Expert Solution

Answer 26

Explanation of Solution

Pictorial presentation: Fig.3 shows structure of serine, where the potential hydrogen bond donors and acceptors are identified.

FUNDAMENTALS OF BIOCHEMISTRY WPNG 1-SEME, Chapter 2, Problem 1E , additional homework tip 3

Fig.3: Serine

The given formula of Fig.3 is identified as serine. Here, at H₃N⁺ position, the hydrogen bond is donated as nitrogen acts as a hydrogen bond donor when it is paired with a hydrogen atom. When nitrogen is not paired with a hydrogen atom, it acts as a hydrogen acceptor. Therefore, at H₃N⁺ group and OH group, the hydrogen bond acts like a donor and COO and OH position, the hydrogen bond acts like an acceptor.