CHEMISTRY:MOLECULAR NATURE (LL)W/ACCESS
7th Edition
ISBN: 9781119497325
Author: JESPERSEN
Publisher: WILEY
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Textbook Question
Chapter 2, Problem 102RQ
Name the following molecular compounds:
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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?
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
0/5
?
مله
Ar
Chapter 2 Solutions
CHEMISTRY:MOLECULAR NATURE (LL)W/ACCESS
Ch. 2 - Practice Exercise 2.11
How many atoms of each...Ch. 2 - Prob. 2PECh. 2 - How many atoms of each clement appear on each side...Ch. 2 - Prob. 4PECh. 2 - Prob. 5PECh. 2 - Prob. 6PECh. 2 - Prob. 7PECh. 2 - Write the formulas for the compounds made from (a)...Ch. 2 - Practice Exercise 2.9 Write all the formulas for...Ch. 2 - Prob. 10PE
Ch. 2 - Prob. 11PECh. 2 - Practice Exercise 2.12
Write the formula for the...Ch. 2 - Prob. 13PECh. 2 - Prob. 14PECh. 2 - Prob. 15PECh. 2 - Prob. 16PECh. 2 - Prob. 17PECh. 2 - Write the formulas for (a) potassium chlorate, (b)...Ch. 2 - Prob. 19PECh. 2 - Prob. 20PECh. 2 - Practice Exercise 2.21
Name the following...Ch. 2 - Practice Exercise 2.22
Write formulas for the...Ch. 2 - Prob. 23PECh. 2 - Prob. 24PECh. 2 - 2.1 In the compounds formed by with chlorine, how...Ch. 2 - Prob. 2RQCh. 2 - Prob. 3RQCh. 2 - 2.4 In the refining of copper, sizable amounts of...Ch. 2 - 2.5 Why would you reasonably expect cadmium to be...Ch. 2 - 2.6 Using the symbol for nitrogen, 147N02,...Ch. 2 - Make a rough sketch of the periodic table and mark...Ch. 2 - Prob. 8RQCh. 2 - Prob. 9RQCh. 2 - Prob. 10RQCh. 2 - Which nonmetals occur as monatomic gases (i.e.,...Ch. 2 - Prob. 12RQCh. 2 - Which physical property of metalloids...Ch. 2 - Sketch the shape of the periodic table and mark...Ch. 2 - Most periodic tables have a heavy line that looks...Ch. 2 - Prob. 16RQCh. 2 - Prob. 17RQCh. 2 - Prob. 18RQCh. 2 - 2.19 What are two ways to interpret a chemical...Ch. 2 - Prob. 20RQCh. 2 - Prob. 21RQCh. 2 - 2.22 Atoms of which elements are usually...Ch. 2 - 2.23 Atoms of which elements are usually...Ch. 2 - A DNA molecule is small in actual size but...Ch. 2 - What do we mean when we say a chemical equation is...Ch. 2 - 2.26 For a chemical reaction, what do we mean by...Ch. 2 - 2.27 The combustion of a thin wire of magnesium...Ch. 2 - Describe what kind of event must occur (involving...Ch. 2 - With what kind of elements do metals react?Ch. 2 - What is an ion? How does it differ from an atom or...Ch. 2 - 2.31 Why do we use the term formula unit for ionic...Ch. 2 - Prob. 32RQCh. 2 - Prob. 33RQCh. 2 - 2.34 How many electrons has a titanium atom lost...Ch. 2 - 2.35 If an atom gains an electron to become an...Ch. 2 - 2.36 How many electrons has a nitrogen atom gained...Ch. 2 - Prob. 37RQCh. 2 - Prob. 38RQCh. 2 - Prob. 39RQCh. 2 - Prob. 40RQCh. 2 - 2.41 What are the formulas (including charges) for...Ch. 2 - Prob. 42RQCh. 2 - Prob. 43RQCh. 2 - 2.44 Write the correct formulas for the compounds...Ch. 2 - 2.45 Write the unbalanced equations for the...Ch. 2 - 2.46 Write the unbalanced equations for the...Ch. 2 - 2.47 With what kind of elements do nonmetals...Ch. 2 - Which are the only elements that exist as free,...Ch. 2 - Prob. 49RQCh. 2 - 2.50 Which kind of elements normally combine to...Ch. 2 - Prob. 51RQCh. 2 - Prob. 52RQCh. 2 - 2.53 Without referring to Table 2.6 but using the...Ch. 2 - Prob. 54RQCh. 2 - 2.55 Astatine, a member of the halogen family,...Ch. 2 - Prob. 56RQCh. 2 - Write the chemical formulas for (a) methane, (b)...Ch. 2 - Prob. 58RQCh. 2 - Prob. 59RQCh. 2 - Prob. 60RQCh. 2 - Prob. 61RQCh. 2 - What is the difference between a binary compound...Ch. 2 - Prob. 64RQCh. 2 - Prob. 65RQCh. 2 - Prob. 66RQCh. 2 - 2.67 The compound is used in the tanning of...Ch. 2 - Asbestos, a known cancer-causing agent, has a...Ch. 2 - 2.69 Epsom salts is a hydrate of magnesium...Ch. 2 - Prob. 70RQCh. 2 - Prob. 71RQCh. 2 - Prob. 72RQCh. 2 - Write the chemical formula for the molecule...Ch. 2 - Write the chemical formula for the molecule...Ch. 2 - Prob. 75RQCh. 2 - Prob. 76RQCh. 2 - 2.77 How many atoms of each element are...Ch. 2 - 2.78 How many atoms of each kind are represented...Ch. 2 - 2.79 How many atoms of each kind are represented...Ch. 2 - 2.80 How many atoms of each kind are represented...Ch. 2 - Prob. 81RQCh. 2 - How many atoms of each element are represented in...Ch. 2 - 2.83 Consider the balanced equation
(a) How many...Ch. 2 - 2.84 Consider the balanced equation for the...Ch. 2 - Prob. 85RQCh. 2 - Prob. 86RQCh. 2 - Is the following chemical equation for the...Ch. 2 - 2.88 Is the following chemical equation balanced?...Ch. 2 - 2.89 Use the periodic table, but not Table 2.2, to...Ch. 2 - 2.90 Use the periodic table, but not Table 2.2, to...Ch. 2 - Prob. 91RQCh. 2 - Prob. 92RQCh. 2 - Prob. 93RQCh. 2 - Prob. 94RQCh. 2 - Prob. 95RQCh. 2 - Prob. 96RQCh. 2 - Prob. 97RQCh. 2 - Prob. 98RQCh. 2 - Prob. 99RQCh. 2 - Prob. 100RQCh. 2 - Prob. 101RQCh. 2 - Name the following molecular compounds:...Ch. 2 - Prob. 103RQCh. 2 - Prob. 104RQCh. 2 - Prob. 105RQCh. 2 - Prob. 106RQCh. 2 - Prob. 107RQCh. 2 - Identify each of the following as molecular or...Ch. 2 - Prob. 109RQCh. 2 - Prob. 110RQCh. 2 - Prob. 111RQCh. 2 - Prob. 112RQCh. 2 - 2.113 Which of the following formulas are...Ch. 2 - Which of the following formulas are incorrect?...Ch. 2 - Prob. 115RQCh. 2 - Prob. 116RQCh. 2 - The compounds Se2S6andSe2S4 have been shown to be...Ch. 2 - Prob. 118RQCh. 2 - The following are models of molecules of two...Ch. 2 - A student obtained a sample from an experiment...Ch. 2 - 2.121 Suppose you wanted, to separate the sample...Ch. 2 - 2.122 The elements in Group 1A and Group 7A of the...Ch. 2 - Prob. 123RQCh. 2 - Prob. 124RQCh. 2 - 2.125 Write the balanced chemical equation for the...Ch. 2 - 2.126 Write the balanced gas phase chemical...Ch. 2 - Bromine is a diatomic molecule, and it has two...Ch. 2 - Prob. 128RQCh. 2 - Prob. 129RQCh. 2 - Prob. 130RQCh. 2 - Prob. 131RQCh. 2 - Explore the internet and find a reliable source of...Ch. 2 - Spreadsheet applications such as Microsoft Excel...
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