CHEMISTRY:MOLECULAR NATURE (LL)W/ACCESS
7th Edition
ISBN: 9781119497325
Author: JESPERSEN
Publisher: WILEY
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Question
Chapter 2, Problem 81RQ
Interpretation Introduction
Interpretation:
The number of atoms of each element which are represented in each of the given expressions, is to be determined.
Concept Information:
A substance which is made up of a definite amount of two or more elements is known as a compound.
A group of atoms which are bonded together and represents the smallest fundamental unit of a chemical compound which can participate in a
A chemical formula of a compound helps in finding the number of atoms of the respective elements which are present in that compound.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 2 Solutions
CHEMISTRY:MOLECULAR NATURE (LL)W/ACCESS
Ch. 2 - Practice Exercise 2.11
How many atoms of each...Ch. 2 - Prob. 2PECh. 2 - How many atoms of each clement appear on each side...Ch. 2 - Prob. 4PECh. 2 - Prob. 5PECh. 2 - Prob. 6PECh. 2 - Prob. 7PECh. 2 - Write the formulas for the compounds made from (a)...Ch. 2 - Practice Exercise 2.9 Write all the formulas for...Ch. 2 - Prob. 10PE
Ch. 2 - Prob. 11PECh. 2 - Practice Exercise 2.12
Write the formula for the...Ch. 2 - Prob. 13PECh. 2 - Prob. 14PECh. 2 - Prob. 15PECh. 2 - Prob. 16PECh. 2 - Prob. 17PECh. 2 - Write the formulas for (a) potassium chlorate, (b)...Ch. 2 - Prob. 19PECh. 2 - Prob. 20PECh. 2 - Practice Exercise 2.21
Name the following...Ch. 2 - Practice Exercise 2.22
Write formulas for the...Ch. 2 - Prob. 23PECh. 2 - Prob. 24PECh. 2 - 2.1 In the compounds formed by with chlorine, how...Ch. 2 - Prob. 2RQCh. 2 - Prob. 3RQCh. 2 - 2.4 In the refining of copper, sizable amounts of...Ch. 2 - 2.5 Why would you reasonably expect cadmium to be...Ch. 2 - 2.6 Using the symbol for nitrogen, 147N02,...Ch. 2 - Make a rough sketch of the periodic table and mark...Ch. 2 - Prob. 8RQCh. 2 - Prob. 9RQCh. 2 - Prob. 10RQCh. 2 - Which nonmetals occur as monatomic gases (i.e.,...Ch. 2 - Prob. 12RQCh. 2 - Which physical property of metalloids...Ch. 2 - Sketch the shape of the periodic table and mark...Ch. 2 - Most periodic tables have a heavy line that looks...Ch. 2 - Prob. 16RQCh. 2 - Prob. 17RQCh. 2 - Prob. 18RQCh. 2 - 2.19 What are two ways to interpret a chemical...Ch. 2 - Prob. 20RQCh. 2 - Prob. 21RQCh. 2 - 2.22 Atoms of which elements are usually...Ch. 2 - 2.23 Atoms of which elements are usually...Ch. 2 - A DNA molecule is small in actual size but...Ch. 2 - What do we mean when we say a chemical equation is...Ch. 2 - 2.26 For a chemical reaction, what do we mean by...Ch. 2 - 2.27 The combustion of a thin wire of magnesium...Ch. 2 - Describe what kind of event must occur (involving...Ch. 2 - With what kind of elements do metals react?Ch. 2 - What is an ion? How does it differ from an atom or...Ch. 2 - 2.31 Why do we use the term formula unit for ionic...Ch. 2 - Prob. 32RQCh. 2 - Prob. 33RQCh. 2 - 2.34 How many electrons has a titanium atom lost...Ch. 2 - 2.35 If an atom gains an electron to become an...Ch. 2 - 2.36 How many electrons has a nitrogen atom gained...Ch. 2 - Prob. 37RQCh. 2 - Prob. 38RQCh. 2 - Prob. 39RQCh. 2 - Prob. 40RQCh. 2 - 2.41 What are the formulas (including charges) for...Ch. 2 - Prob. 42RQCh. 2 - Prob. 43RQCh. 2 - 2.44 Write the correct formulas for the compounds...Ch. 2 - 2.45 Write the unbalanced equations for the...Ch. 2 - 2.46 Write the unbalanced equations for the...Ch. 2 - 2.47 With what kind of elements do nonmetals...Ch. 2 - Which are the only elements that exist as free,...Ch. 2 - Prob. 49RQCh. 2 - 2.50 Which kind of elements normally combine to...Ch. 2 - Prob. 51RQCh. 2 - Prob. 52RQCh. 2 - 2.53 Without referring to Table 2.6 but using the...Ch. 2 - Prob. 54RQCh. 2 - 2.55 Astatine, a member of the halogen family,...Ch. 2 - Prob. 56RQCh. 2 - Write the chemical formulas for (a) methane, (b)...Ch. 2 - Prob. 58RQCh. 2 - Prob. 59RQCh. 2 - Prob. 60RQCh. 2 - Prob. 61RQCh. 2 - What is the difference between a binary compound...Ch. 2 - Prob. 64RQCh. 2 - Prob. 65RQCh. 2 - Prob. 66RQCh. 2 - 2.67 The compound is used in the tanning of...Ch. 2 - Asbestos, a known cancer-causing agent, has a...Ch. 2 - 2.69 Epsom salts is a hydrate of magnesium...Ch. 2 - Prob. 70RQCh. 2 - Prob. 71RQCh. 2 - Prob. 72RQCh. 2 - Write the chemical formula for the molecule...Ch. 2 - Write the chemical formula for the molecule...Ch. 2 - Prob. 75RQCh. 2 - Prob. 76RQCh. 2 - 2.77 How many atoms of each element are...Ch. 2 - 2.78 How many atoms of each kind are represented...Ch. 2 - 2.79 How many atoms of each kind are represented...Ch. 2 - 2.80 How many atoms of each kind are represented...Ch. 2 - Prob. 81RQCh. 2 - How many atoms of each element are represented in...Ch. 2 - 2.83 Consider the balanced equation
(a) How many...Ch. 2 - 2.84 Consider the balanced equation for the...Ch. 2 - Prob. 85RQCh. 2 - Prob. 86RQCh. 2 - Is the following chemical equation for the...Ch. 2 - 2.88 Is the following chemical equation balanced?...Ch. 2 - 2.89 Use the periodic table, but not Table 2.2, to...Ch. 2 - 2.90 Use the periodic table, but not Table 2.2, to...Ch. 2 - Prob. 91RQCh. 2 - Prob. 92RQCh. 2 - Prob. 93RQCh. 2 - Prob. 94RQCh. 2 - Prob. 95RQCh. 2 - Prob. 96RQCh. 2 - Prob. 97RQCh. 2 - Prob. 98RQCh. 2 - Prob. 99RQCh. 2 - Prob. 100RQCh. 2 - Prob. 101RQCh. 2 - Name the following molecular compounds:...Ch. 2 - Prob. 103RQCh. 2 - Prob. 104RQCh. 2 - Prob. 105RQCh. 2 - Prob. 106RQCh. 2 - Prob. 107RQCh. 2 - Identify each of the following as molecular or...Ch. 2 - Prob. 109RQCh. 2 - Prob. 110RQCh. 2 - Prob. 111RQCh. 2 - Prob. 112RQCh. 2 - 2.113 Which of the following formulas are...Ch. 2 - Which of the following formulas are incorrect?...Ch. 2 - Prob. 115RQCh. 2 - Prob. 116RQCh. 2 - The compounds Se2S6andSe2S4 have been shown to be...Ch. 2 - Prob. 118RQCh. 2 - The following are models of molecules of two...Ch. 2 - A student obtained a sample from an experiment...Ch. 2 - 2.121 Suppose you wanted, to separate the sample...Ch. 2 - 2.122 The elements in Group 1A and Group 7A of the...Ch. 2 - Prob. 123RQCh. 2 - Prob. 124RQCh. 2 - 2.125 Write the balanced chemical equation for the...Ch. 2 - 2.126 Write the balanced gas phase chemical...Ch. 2 - Bromine is a diatomic molecule, and it has two...Ch. 2 - Prob. 128RQCh. 2 - Prob. 129RQCh. 2 - Prob. 130RQCh. 2 - Prob. 131RQCh. 2 - Explore the internet and find a reliable source of...Ch. 2 - Spreadsheet applications such as Microsoft Excel...
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