The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene. Concept Introduction: Nomenclature of benzene and its derivative compounds: Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene. When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound. Nomenclature of benzene compound with more substituents, If one of the substituents imparts a special name, name the molecule as a derivative of that parent. If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”. Example: To indicate relative position on a benzene ring, three terms are mainly used and they are, (1) Ortho-(o): On adjacent carbons (1,2) (2) Meta-(m): Separated by one carbon (1,3) (3) Para-(p): Separated by two carbons (1,4)

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Answer 1

Question

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

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Answer 2

Question

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

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Answer 3

Question

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

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Answer 4

Question

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

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Answer 5

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 6

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 7

Chapter 19.13, Problem 14P

(a)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 2,4,6-tribromobenzene.

Concept Introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 8

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 9

(b)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 3-hydroxynitrobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 10

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 11

(c)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound para-methylbromobenzene

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 12

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 13

(d)

Interpretation Introduction

Interpretation: The correct name should be given for the incorrectly named organic compound 1,6-dichlorobenzene.

Concept introduction:

Nomenclature of benzene and its derivative compounds:

Monosubstituted alkylbenzenes are named as derivatives of benzene; for example butylbenzene.

When one of the special case compounds (example aniline, toluene, phenol…) is involved, the compound is named as a derivative of the special compound.

Nomenclature of benzene compound with more substituents,

If one of the substituents imparts a special name, name the molecule as a derivative of that parent.

If none of the substituents imparts a special name, number the substituents to give the smallest set of numbers, and list them in alphabetical order before the ending “benzene”.

Example:

To indicate relative position on a benzene ring, three terms are mainly used and they are,

(1) Ortho-(o): On adjacent carbons (1,2)

(2) Meta-(m): Separated by one carbon (1,3)

(3) Para-(p): Separated by two carbons (1,4)

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19.1 - Draw the structure for each of the following: a....Ch. 19.2 - PROBLEM 2 If electrophilic addition to benzene is...Ch. 19.4 - Why does hydration inactivate FeBr3?Ch. 19.6 - Prob. 5P Ch. 19.7 - Prob. 6P Ch. 19.8 - What is the major product of a Friedel-Crafts...Ch. 19.10 - Describe two ways to prepare each of the following...Ch. 19.12 - Prob. 9P Ch. 19.13 - Name the following:Ch. 19.13 - Prob. 12P

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