The structure of the compound m-ethylphenol has to be drawn. Concept Introduction: Criteria for substitution in benzene ring: The groups present on first and second position on benzene ring are said to be at ortho position. The groups present on first and third position on benzene ring are said to be at meta position. The groups present on first and fourth position on benzene ring are said to be at pera position.

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Answer 1

Question

Chapter 19, Problem 49P

(a)

Interpretation Introduction

Interpretation:

The structure of the compound m-ethylphenol has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(b)

Interpretation Introduction

Interpretation:

The structure of the compound p-nitrobenzenesulfonic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(c)

Interpretation Introduction

Interpretation:

The structure of the compound (E)-2-phenyl-2-pentene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(d)

Interpretation Introduction

Interpretation:

The structure of the compound o-bromoaniline has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(e)

Interpretation Introduction

Interpretation:

The structure of the compound 4-bromo-1-chloro-2-methylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(f)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorostyrene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(g)

Interpretation Introduction

Interpretation:

The structure of the compound o-nitroanisole has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(h)

Interpretation Introduction

Interpretation:

The structure of the compound 2,4-dichloromethylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(i)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorobenzoic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

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Answer 2

Question

Chapter 19, Problem 49P

(a)

Interpretation Introduction

Interpretation:

The structure of the compound m-ethylphenol has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(b)

Interpretation Introduction

Interpretation:

The structure of the compound p-nitrobenzenesulfonic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(c)

Interpretation Introduction

Interpretation:

The structure of the compound (E)-2-phenyl-2-pentene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(d)

Interpretation Introduction

Interpretation:

The structure of the compound o-bromoaniline has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(e)

Interpretation Introduction

Interpretation:

The structure of the compound 4-bromo-1-chloro-2-methylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(f)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorostyrene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(g)

Interpretation Introduction

Interpretation:

The structure of the compound o-nitroanisole has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(h)

Interpretation Introduction

Interpretation:

The structure of the compound 2,4-dichloromethylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(i)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorobenzoic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

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Answer 3

Question

Chapter 19, Problem 49P

(a)

Interpretation Introduction

Interpretation:

The structure of the compound m-ethylphenol has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(b)

Interpretation Introduction

Interpretation:

The structure of the compound p-nitrobenzenesulfonic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(c)

Interpretation Introduction

Interpretation:

The structure of the compound (E)-2-phenyl-2-pentene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(d)

Interpretation Introduction

Interpretation:

The structure of the compound o-bromoaniline has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(e)

Interpretation Introduction

Interpretation:

The structure of the compound 4-bromo-1-chloro-2-methylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(f)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorostyrene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(g)

Interpretation Introduction

Interpretation:

The structure of the compound o-nitroanisole has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(h)

Interpretation Introduction

Interpretation:

The structure of the compound 2,4-dichloromethylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(i)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorobenzoic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

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Answer 4

Question

Chapter 19, Problem 49P

(a)

Interpretation Introduction

Interpretation:

The structure of the compound m-ethylphenol has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(b)

Interpretation Introduction

Interpretation:

The structure of the compound p-nitrobenzenesulfonic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(c)

Interpretation Introduction

Interpretation:

The structure of the compound (E)-2-phenyl-2-pentene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(d)

Interpretation Introduction

Interpretation:

The structure of the compound o-bromoaniline has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(e)

Interpretation Introduction

Interpretation:

The structure of the compound 4-bromo-1-chloro-2-methylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(f)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorostyrene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(g)

Interpretation Introduction

Interpretation:

The structure of the compound o-nitroanisole has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(h)

Interpretation Introduction

Interpretation:

The structure of the compound 2,4-dichloromethylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(i)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorobenzoic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

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Answer 5

Chapter 19, Problem 49P

(a)

Interpretation Introduction

Interpretation:

The structure of the compound m-ethylphenol has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(b)

Interpretation Introduction

Interpretation:

The structure of the compound p-nitrobenzenesulfonic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(c)

Interpretation Introduction

Interpretation:

The structure of the compound (E)-2-phenyl-2-pentene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(d)

Interpretation Introduction

Interpretation:

The structure of the compound o-bromoaniline has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(e)

Interpretation Introduction

Interpretation:

The structure of the compound 4-bromo-1-chloro-2-methylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(f)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorostyrene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(g)

Interpretation Introduction

Interpretation:

The structure of the compound o-nitroanisole has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(h)

Interpretation Introduction

Interpretation:

The structure of the compound 2,4-dichloromethylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

(i)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorobenzoic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 6

Chapter 19, Problem 49P

(a)

Interpretation Introduction

Interpretation:

The structure of the compound m-ethylphenol has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 7

Chapter 19, Problem 49P

(a)

Interpretation Introduction

Interpretation:

The structure of the compound m-ethylphenol has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of the compound p-nitrobenzenesulfonic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of the compound p-nitrobenzenesulfonic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structure of the compound (E)-2-phenyl-2-pentene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structure of the compound (E)-2-phenyl-2-pentene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of the compound o-bromoaniline has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of the compound o-bromoaniline has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The structure of the compound 4-bromo-1-chloro-2-methylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The structure of the compound 4-bromo-1-chloro-2-methylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorostyrene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorostyrene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 18

(g)

Interpretation Introduction

Interpretation:

The structure of the compound o-nitroanisole has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The structure of the compound o-nitroanisole has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 20

(h)

Interpretation Introduction

Interpretation:

The structure of the compound 2,4-dichloromethylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 21

(h)

Interpretation Introduction

Interpretation:

The structure of the compound 2,4-dichloromethylbenzene has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 22

(i)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorobenzoic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 23

(i)

Interpretation Introduction

Interpretation:

The structure of the compound m-chlorobenzoic acid has to be drawn.

Concept Introduction:

Criteria for substitution in benzene ring:

The groups present on first and second position on benzene ring are said to be at ortho position.

The groups present on first and third position on benzene ring are said to be at meta position.

The groups present on first and fourth position on benzene ring are said to be at pera position.

Answer 24

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Answer 25

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Answer 26

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Answer 27

Ch. 19.1 - Draw the structure for each of the following: a....Ch. 19.2 - PROBLEM 2 If electrophilic addition to benzene is...Ch. 19.4 - Why does hydration inactivate FeBr3?Ch. 19.6 - Prob. 5P Ch. 19.7 - Prob. 6P Ch. 19.8 - What is the major product of a Friedel-Crafts...Ch. 19.10 - Describe two ways to prepare each of the following...Ch. 19.12 - Prob. 9P Ch. 19.13 - Name the following:Ch. 19.13 - Prob. 12P

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Chapter 19 Solutions