a) Interpretation: The name of the ketone shown is to be given. Concept introduction: Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo. To give: The name of the ketone shown.

Question

81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia

Answer 1

Question

Chapter 19.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the ketone shown.

Interpretation Introduction

b)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

c)

Interpretation:

The name of the diketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the diketone shown.

Interpretation Introduction

d)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the -CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

e)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

f)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. For alicyclic ketones the number of carbons in the ring determines the parent name. The numbering starts from the carbonyl carbon and the numbering is done such a way that other functional groups and/or substituents get the lowest possible number.

To give:

The name of the ketone shown.

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81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Answer 2

Question

Chapter 19.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the ketone shown.

Interpretation Introduction

b)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

c)

Interpretation:

The name of the diketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the diketone shown.

Interpretation Introduction

d)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the -CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

e)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

f)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. For alicyclic ketones the number of carbons in the ring determines the parent name. The numbering starts from the carbonyl carbon and the numbering is done such a way that other functional groups and/or substituents get the lowest possible number.

To give:

The name of the ketone shown.

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Answer 3

Question

Chapter 19.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the ketone shown.

Interpretation Introduction

b)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

c)

Interpretation:

The name of the diketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the diketone shown.

Interpretation Introduction

d)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the -CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

e)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

f)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. For alicyclic ketones the number of carbons in the ring determines the parent name. The numbering starts from the carbonyl carbon and the numbering is done such a way that other functional groups and/or substituents get the lowest possible number.

To give:

The name of the ketone shown.

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Answer 4

Question

Chapter 19.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the ketone shown.

Interpretation Introduction

b)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

c)

Interpretation:

The name of the diketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the diketone shown.

Interpretation Introduction

d)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the -CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

e)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

f)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. For alicyclic ketones the number of carbons in the ring determines the parent name. The numbering starts from the carbonyl carbon and the numbering is done such a way that other functional groups and/or substituents get the lowest possible number.

To give:

The name of the ketone shown.

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Answer 5

Chapter 19.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the ketone shown.

Interpretation Introduction

b)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

c)

Interpretation:

The name of the diketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the diketone shown.

Interpretation Introduction

d)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the -CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

e)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Interpretation Introduction

f)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. For alicyclic ketones the number of carbons in the ring determines the parent name. The numbering starts from the carbonyl carbon and the numbering is done such a way that other functional groups and/or substituents get the lowest possible number.

To give:

The name of the ketone shown.

Answer 6

Chapter 19.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the ketone shown.

Answer 7

Chapter 19.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the ketone shown.

Answer 8

Interpretation Introduction

b)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Answer 10

Interpretation Introduction

c)

Interpretation:

The name of the diketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the diketone shown.

Answer 11

Interpretation Introduction

c)

Interpretation:

The name of the diketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. The parent chain is the longest one that includes the ketone group and the numbering begins at the end nearer to the carbonyl carbon. If other functional groups are present the double bonded oxygen is considered as a substituent on the parent chain with the prefix –oxo.

To give:

The name of the diketone shown.

Answer 12

Interpretation Introduction

d)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the -CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Answer 13

Interpretation Introduction

d)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the -CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Answer 14

Interpretation Introduction

e)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Answer 15

Interpretation Introduction

e)

Interpretation:

The name of the aldehyde shown is to be given.

Concept introduction:

Aldehydes are named by replacing the terminal –e of the parent alkane with –al. The parent chain is the longest one that includes the –CHO group and the –CHO group is numbered as carbon 1. For cyclic aldehydes in which the –CHO group is directly attached to the ring, the suffix –carbaldehyde is used.

To give:

The name of the aldehyde shown.

Answer 16

Interpretation Introduction

f)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. For alicyclic ketones the number of carbons in the ring determines the parent name. The numbering starts from the carbonyl carbon and the numbering is done such a way that other functional groups and/or substituents get the lowest possible number.

To give:

The name of the ketone shown.

Answer 17

Interpretation Introduction

f)

Interpretation:

The name of the ketone shown is to be given.

Concept introduction:

Ketones are named by replacing the terminal –e of the parent alkane with –one. For alicyclic ketones the number of carbons in the ring determines the parent name. The numbering starts from the carbonyl carbon and the numbering is done such a way that other functional groups and/or substituents get the lowest possible number.

To give:

The name of the ketone shown.

Answer 18

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Answer 19

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Answer 23

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Answer 24

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Answer 25

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Answer 29

Ch. 19.1 - Prob. 1P Ch. 19.1 - Draw structures corresponding to the following...Ch. 19.2 - Prob. 3P Ch. 19.2 - How would you carry out the following reactions?...Ch. 19.4 - Treatment of an aldehyde or ketone with cyanide...Ch. 19.4 - p-Nitrobenzaldehyde is more reactive toward...Ch. 19.5 - Prob. 7P Ch. 19.5 - The oxygen in water is primarily (99.8) 16O, but...Ch. 19.6 - Prob. 9P Ch. 19.8 - Show the products you would obtain by...

Solution Summary: The author explains that the name of the ketone shown is 2-methylpentan-3-one.

Chapter 19 Solutions