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Consider a galvanic cell consisting of a magnesium electrode in contact with
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- A voltaic cell is constructed in which one half-cell consists of a silver wire in an aqueous solution of AgNO3.The other half cell consists of an inert platinum wire in an aqueous solution containing Fe2+(aq) and Fe3+(aq). (a) Calculate the cell potential, assuming standard conditions. (b) Write the net ionic equation for the reaction occurring in the cell. (c) Which electrode is the anode and which is the cathode? (d) If [Ag+] is 0.10 M, and [Fe2+] and [Fe3+] are both 1.0 M, what is the cell potential? Is the net cell reaction still that used in part (a)? If not, what is the net reaction under the new conditions?arrow_forwardAn electrolysis experiment is performed to determine the value of the Faraday constant (number of coulombs per mole of electrons). In this experiment, 28.8 g of gold is plated out from a AuCN solution by running an electrolytic cell for two hours with a current of 2.00 A. What is the experimental value obtained for the Faraday Constant?arrow_forwardAn electrode is prepared from liquid mercury in contact with a saturated solution of mercury(I) chloride, Hg2Cl, containing 1.00 M Cl . The cell potential of the voltaic cell constructed by connecting this electrode as the cathode to the standard hydrogen half-cell as the anode is 0.268 V. What is the solubility product of mercury(I) chloride?arrow_forward
- Assume the following electrochemical cell simulates the galvanic cell formed by copper and zinc in seawater at pH 7.90 and 25 C. Zn | Zn(OH)2(s) | OH(aq) || Cu(OH)2(s) | Cu(s) a. Write a balanced equation for the reaction that occurs at the cathode. b. Write a balanced equation for the reaction that occurs at the anode. c. Write a balanced chemical equation for the overall reaction. d. Determine the potential (in volts) of the cell.arrow_forwardConsider the electrolysis of water in the presence of very dilute H2SO4. What species is produced at the anode? Atthe cathode? What are the relative amounts of the speciesproduced at the two electrodes?arrow_forwarda Calculate the equilibrium constant for the following reaction at 25C. Sn(s)+Pb2+(aq)Sn2+(aq)+Pb(s) The standard cell potential of the corresponding voltaic cell is 0.010 V. b If an excess of tin metal is added to 1.0 M Pb2+, what is the concentration of Pb2+ at equilibrium?arrow_forward
- An aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forwardAn electrode is prepared by dipping a silver strip into a solution saturated with silver thiocyanate, AgSCN, and containing 0.10 M SCN . The cell potential of the voltaic cell constructed by connecting this electrode as the cathode to the standard hydrogen half-cell as the anode is 0.45 V. What is the solubility product of silver thiocyanate?arrow_forwardYou have 1.0 M solutions of Al(NO3)3 and AgNO3 along with Al and Ag electrodes to construct a voltaic cell. The salt bridge contains a saturated solution of KCl. Complete the picture associated with this problem by a writing the symbols of the elements and ions in the appropriate areas (both solutions and electrodes). b identifying the anode and cathode. c indicating the direction of electron flow through the external circuit. d indicating the cell potential (assume standard conditions, with no current flowing). e writing the appropriate half-reaction under each of the containers. f indicating the direction of ion flow in the salt bridge. g identifying the species undergoing oxidation and reduction. h writing the balanced overall reaction for the cell.arrow_forward
- Hydrazine, N2H4, has been proposed as the fuel in a fuel cell in which oxygen is the oxidizing agent. The reactions are N2H4(aq) + 4 OH(aq) N2(g) + 4 H2O() + 4e O2(g) + 2 H2O() + 4e 4 OH(aq) (a) Which reaction occurs at the anode and which at thecathode? (b) What is the overall cell reaction? (c) If the cell is to produce 0.50 A of current for 50.0 h, calculate what mass in grams of hydrazine must be present. (d) Calculate what mass (g) of O2 must be available to reactwith the mass of N2H4 determined in part (c).arrow_forwardFrom the information provided, use cell notation to describe the following systems: (a) In one half-cell, a solution of Pt(NO3)2 forms Pt metal, while in the other half-Cell, Cu metal goes into a.Cu(NO3)2 solution with all solute concentrations 1 M. (b) The cathode consists of a gold electrode in a 0.55 M Au(NO3)3 solution and the anode is a magnesium electrode in 0.75 M Mg(NO3)2 solution. (c) One half-cell consists of a silver electrode in a 1 M AgNO3 solution, and in the other half-cell, a copper Electrode in 1 M Cu(NO3)2 is oxidized.arrow_forwardConsider a galvanic cell based on the following half-reactions: a. What is the standard potential for this cell? b. A nonstandard cell is set up at 25C with [Mg2+] = 1.00 105 M. The cell potential is observed to be 4.01 V. Calculate [Au3+] in this cell.arrow_forward
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