(a) Interpretation: Whether the structure of cyclohexene is saturated or unsaturated is to be predicted. Concept introduction: A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

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Answer 1

Question

Chapter 19, Problem 78E

Interpretation Introduction

(a)

Interpretation:

Whether the structure of cyclohexene is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Interpretation Introduction

(b)

Interpretation:

Whether the structure of cyclopropane is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 19, Problem 78E

Interpretation Introduction

(a)

Interpretation:

Whether the structure of cyclohexene is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Interpretation Introduction

(b)

Interpretation:

Whether the structure of cyclopropane is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

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Answer 3

Question

Chapter 19, Problem 78E

Interpretation Introduction

(a)

Interpretation:

Whether the structure of cyclohexene is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Interpretation Introduction

(b)

Interpretation:

Whether the structure of cyclopropane is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

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Answer 4

Question

Chapter 19, Problem 78E

Interpretation Introduction

(a)

Interpretation:

Whether the structure of cyclohexene is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Interpretation Introduction

(b)

Interpretation:

Whether the structure of cyclopropane is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

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Answer 5

Chapter 19, Problem 78E

Interpretation Introduction

(a)

Interpretation:

Whether the structure of cyclohexene is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Interpretation Introduction

(b)

Interpretation:

Whether the structure of cyclopropane is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Answer 6

Chapter 19, Problem 78E

Interpretation Introduction

(a)

Interpretation:

Whether the structure of cyclohexene is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Answer 7

Chapter 19, Problem 78E

Interpretation Introduction

(a)

Interpretation:

Whether the structure of cyclohexene is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the structure of cyclopropane is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the structure of cyclopropane is saturated or unsaturated is to be predicted.

Concept introduction:

A saturated compound is defined as a compound in which a carbon chain consists of carbon atoms linked with a single bond. An unsaturated compound is a compound in which a carbon chain is linked with carbon atoms bonded by double or triple bonds.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19 - Prob. 1CE Ch. 19 - Prob. 2CE Ch. 19 - Prob. 3CE Ch. 19 - Prob. 4CE Ch. 19 - Prob. 5CE Ch. 19 - Prob. 6CE Ch. 19 - Prob. 7CE Ch. 19 - Prob. 1KT Ch. 19 - Prob. 2KT Ch. 19 - Prob. 3KT

Solution Summary: The author explains that cyclohexene is an unsaturated compound.

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