(a) Interpretation: The simplest formula of the given compounds is to be written. Concept introduction: The simplest molecular formula is also known as the empirical formula. It represents the simplest ratio of element present in a compound. The formula is written in the form of element symbol and its mole ratio in its subscript.

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Answer 1

Question

Chapter 19, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The simplest formula of the given compounds is to be written.

Concept introduction:

The simplest molecular formula is also known as the empirical formula. It represents the simplest ratio of element present in a compound. The formula is written in the form of element symbol and its mole ratio in its subscript.

Interpretation Introduction

(b)

Interpretation:

The structural formula should be drawn for the complex formed.

Concept introduction:

The geometry of any complex is the spatial arrangement of ligands around the central metal cation. The chemical and most of the physical properties of the complex depends on this geometrical arrangement only.

When the same ligands are on the same side around central atom, then the arrangement is ‘cis’ while the same ligands are arranged on opposite side of the central atom shows a “trans” geometry.

The number of ligands attached to the metal cation shows its co-ordination number.

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Indicate the correct option.a) Graphite conducts electricity, being an isotropic materialb) Graphite is not a conductor of electricityc) Both are false

(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

Answer 2

Question

Chapter 19, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The simplest formula of the given compounds is to be written.

Concept introduction:

The simplest molecular formula is also known as the empirical formula. It represents the simplest ratio of element present in a compound. The formula is written in the form of element symbol and its mole ratio in its subscript.

Interpretation Introduction

(b)

Interpretation:

The structural formula should be drawn for the complex formed.

Concept introduction:

The geometry of any complex is the spatial arrangement of ligands around the central metal cation. The chemical and most of the physical properties of the complex depends on this geometrical arrangement only.

When the same ligands are on the same side around central atom, then the arrangement is ‘cis’ while the same ligands are arranged on opposite side of the central atom shows a “trans” geometry.

The number of ligands attached to the metal cation shows its co-ordination number.

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Answer 3

Question

Chapter 19, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The simplest formula of the given compounds is to be written.

Concept introduction:

The simplest molecular formula is also known as the empirical formula. It represents the simplest ratio of element present in a compound. The formula is written in the form of element symbol and its mole ratio in its subscript.

Interpretation Introduction

(b)

Interpretation:

The structural formula should be drawn for the complex formed.

Concept introduction:

The geometry of any complex is the spatial arrangement of ligands around the central metal cation. The chemical and most of the physical properties of the complex depends on this geometrical arrangement only.

When the same ligands are on the same side around central atom, then the arrangement is ‘cis’ while the same ligands are arranged on opposite side of the central atom shows a “trans” geometry.

The number of ligands attached to the metal cation shows its co-ordination number.

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Answer 4

Question

Chapter 19, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The simplest formula of the given compounds is to be written.

Concept introduction:

The simplest molecular formula is also known as the empirical formula. It represents the simplest ratio of element present in a compound. The formula is written in the form of element symbol and its mole ratio in its subscript.

Interpretation Introduction

(b)

Interpretation:

The structural formula should be drawn for the complex formed.

Concept introduction:

The geometry of any complex is the spatial arrangement of ligands around the central metal cation. The chemical and most of the physical properties of the complex depends on this geometrical arrangement only.

When the same ligands are on the same side around central atom, then the arrangement is ‘cis’ while the same ligands are arranged on opposite side of the central atom shows a “trans” geometry.

The number of ligands attached to the metal cation shows its co-ordination number.

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Answer 5

Chapter 19, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The simplest formula of the given compounds is to be written.

Concept introduction:

The simplest molecular formula is also known as the empirical formula. It represents the simplest ratio of element present in a compound. The formula is written in the form of element symbol and its mole ratio in its subscript.

Interpretation Introduction

(b)

Interpretation:

The structural formula should be drawn for the complex formed.

Concept introduction:

The geometry of any complex is the spatial arrangement of ligands around the central metal cation. The chemical and most of the physical properties of the complex depends on this geometrical arrangement only.

When the same ligands are on the same side around central atom, then the arrangement is ‘cis’ while the same ligands are arranged on opposite side of the central atom shows a “trans” geometry.

The number of ligands attached to the metal cation shows its co-ordination number.

Answer 6

Chapter 19, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The simplest formula of the given compounds is to be written.

Concept introduction:

The simplest molecular formula is also known as the empirical formula. It represents the simplest ratio of element present in a compound. The formula is written in the form of element symbol and its mole ratio in its subscript.

Answer 7

Chapter 19, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The simplest formula of the given compounds is to be written.

Concept introduction:

The simplest molecular formula is also known as the empirical formula. It represents the simplest ratio of element present in a compound. The formula is written in the form of element symbol and its mole ratio in its subscript.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structural formula should be drawn for the complex formed.

Concept introduction:

The geometry of any complex is the spatial arrangement of ligands around the central metal cation. The chemical and most of the physical properties of the complex depends on this geometrical arrangement only.

When the same ligands are on the same side around central atom, then the arrangement is ‘cis’ while the same ligands are arranged on opposite side of the central atom shows a “trans” geometry.

The number of ligands attached to the metal cation shows its co-ordination number.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structural formula should be drawn for the complex formed.

Concept introduction:

The geometry of any complex is the spatial arrangement of ligands around the central metal cation. The chemical and most of the physical properties of the complex depends on this geometrical arrangement only.

When the same ligands are on the same side around central atom, then the arrangement is ‘cis’ while the same ligands are arranged on opposite side of the central atom shows a “trans” geometry.

The number of ligands attached to the metal cation shows its co-ordination number.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19 - Prob. 1QAP Ch. 19 - Prob. 2QAP Ch. 19 - Prob. 3QAP Ch. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAP Ch. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAP Ch. 19 - Prob. 8QAP Ch. 19 - Prob. 9QAP Ch. 19 - Prob. 10QAP

Solution Summary: The author explains that the simplest molecular formula is also known as the empirical formula.

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