(a) Interpretation: The formula of the coordination compound formed by Cu + with NH 3 needs to be determined. Concept introduction: Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 1

Question

Chapter 19, Problem 11QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Cu⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Pt²⁺ with oxalate ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with H₂ O needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Fe³⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

Answer 2

Question

Chapter 19, Problem 11QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Cu⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Pt²⁺ with oxalate ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with H₂ O needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Fe³⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 3

Question

Chapter 19, Problem 11QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Cu⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Pt²⁺ with oxalate ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with H₂ O needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Fe³⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 4

Question

Chapter 19, Problem 11QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Cu⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Pt²⁺ with oxalate ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with H₂ O needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Fe³⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 5

Chapter 19, Problem 11QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Cu⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Pt²⁺ with oxalate ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with H₂ O needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Fe³⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 6

Chapter 19, Problem 11QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Cu⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 7

Chapter 19, Problem 11QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Cu⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Pt²⁺ with oxalate ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Pt²⁺ with oxalate ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with H₂ O needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with H₂ O needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Fe³⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Fe³⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 19 - Prob. 1QAP Ch. 19 - Prob. 2QAP Ch. 19 - Prob. 3QAP Ch. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAP Ch. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAP Ch. 19 - Prob. 8QAP Ch. 19 - Prob. 9QAP Ch. 19 - Prob. 10QAP

Solution Summary: The author explains the formula of the coordination compound formed by Cu + with NH 3 needs to be determined.

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Chapter 19 Solutions