(a) Interpretation: The abbreviated electronic configuration for metal ion Cr 3 + needs to be determined. Concept introduction: A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

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Answer 1

Question

Chapter 19, Problem 31QAP

Interpretation Introduction

(a)

Interpretation:

The abbreviated electronic configuration for metal ion Cr3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(b)

Interpretation:

The abbreviated electronic configuration for metal ion Pd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(c)

Interpretation:

The abbreviated electronic configuration for metal ion V3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(d)

Interpretation:

The abbreviated electronic configuration for metal ion Ir3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(e)

Interpretation:

The abbreviated electronic configuration for metal ion Ru2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;

Answer 2

Question

Chapter 19, Problem 31QAP

Interpretation Introduction

(a)

Interpretation:

The abbreviated electronic configuration for metal ion Cr3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(b)

Interpretation:

The abbreviated electronic configuration for metal ion Pd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(c)

Interpretation:

The abbreviated electronic configuration for metal ion V3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(d)

Interpretation:

The abbreviated electronic configuration for metal ion Ir3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(e)

Interpretation:

The abbreviated electronic configuration for metal ion Ru2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

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Answer 3

Question

Chapter 19, Problem 31QAP

Interpretation Introduction

(a)

Interpretation:

The abbreviated electronic configuration for metal ion Cr3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(b)

Interpretation:

The abbreviated electronic configuration for metal ion Pd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(c)

Interpretation:

The abbreviated electronic configuration for metal ion V3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(d)

Interpretation:

The abbreviated electronic configuration for metal ion Ir3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(e)

Interpretation:

The abbreviated electronic configuration for metal ion Ru2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

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Answer 4

Question

Chapter 19, Problem 31QAP

Interpretation Introduction

(a)

Interpretation:

The abbreviated electronic configuration for metal ion Cr3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(b)

Interpretation:

The abbreviated electronic configuration for metal ion Pd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(c)

Interpretation:

The abbreviated electronic configuration for metal ion V3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(d)

Interpretation:

The abbreviated electronic configuration for metal ion Ir3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(e)

Interpretation:

The abbreviated electronic configuration for metal ion Ru2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

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Answer 5

Chapter 19, Problem 31QAP

Interpretation Introduction

(a)

Interpretation:

The abbreviated electronic configuration for metal ion Cr3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(b)

Interpretation:

The abbreviated electronic configuration for metal ion Pd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(c)

Interpretation:

The abbreviated electronic configuration for metal ion V3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(d)

Interpretation:

The abbreviated electronic configuration for metal ion Ir3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(e)

Interpretation:

The abbreviated electronic configuration for metal ion Ru2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 6

Chapter 19, Problem 31QAP

Interpretation Introduction

(a)

Interpretation:

The abbreviated electronic configuration for metal ion Cr3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 7

Chapter 19, Problem 31QAP

Interpretation Introduction

(a)

Interpretation:

The abbreviated electronic configuration for metal ion Cr3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The abbreviated electronic configuration for metal ion Pd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The abbreviated electronic configuration for metal ion Pd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The abbreviated electronic configuration for metal ion V3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The abbreviated electronic configuration for metal ion V3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The abbreviated electronic configuration for metal ion Ir3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The abbreviated electronic configuration for metal ion Ir3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The abbreviated electronic configuration for metal ion Ru2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The abbreviated electronic configuration for metal ion Ru2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 19 - Prob. 1QAP Ch. 19 - Prob. 2QAP Ch. 19 - Prob. 3QAP Ch. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAP Ch. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAP Ch. 19 - Prob. 8QAP Ch. 19 - Prob. 9QAP Ch. 19 - Prob. 10QAP

Solution Summary: The author explains the abbreviated electronic configuration for metal ion Cr3+ needs to be determined. Electrons are distributed in the five d-orbitals according to

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