Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 19, Problem 31QAP
Interpretation Introduction

(a)

Interpretation:

The abbreviated electronic configuration for metal ion Cr3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(b)

Interpretation:

The abbreviated electronic configuration for metal ion Pd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(c)

Interpretation:

The abbreviated electronic configuration for metal ion V3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(d)

Interpretation:

The abbreviated electronic configuration for metal ion Ir3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(e)

Interpretation:

The abbreviated electronic configuration for metal ion Ru2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s-electrons available for bonding, rather the inner d-electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d-orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

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Chapter 19 Solutions

Chemistry: Principles and Reactions

Ch. 19 - Prob. 11QAPCh. 19 - Prob. 12QAPCh. 19 - What is the mass percent of sulfur in the...Ch. 19 - Prob. 14QAPCh. 19 - There are four iron atoms in each hemoglobin...Ch. 19 - Vitamin B12 is a coordination compound with cobalt...Ch. 19 - Prob. 17QAPCh. 19 - Prob. 18QAPCh. 19 - Name the following ions or compounds (a)...Ch. 19 - Name the following ions or compounds (a)...Ch. 19 - Prob. 21QAPCh. 19 - Prob. 22QAPCh. 19 - Sketch the geometry of (a)...Ch. 19 - Sketch the geometry of (a) tans-[Cu(Br)2(H2O)4]...Ch. 19 - Prob. 25QAPCh. 19 - Prob. 26QAPCh. 19 - Which of the following octahedral complexes show...Ch. 19 - Prob. 28QAPCh. 19 - Prob. 29QAPCh. 19 - Prob. 30QAPCh. 19 - Prob. 31QAPCh. 19 - Prob. 32QAPCh. 19 - Write an abbreviated orbital diagram and determine...Ch. 19 - Prob. 34QAPCh. 19 - Give the electron distribution in low-spin and/or...Ch. 19 - Prob. 36QAPCh. 19 - Prob. 37QAPCh. 19 - Prob. 38QAPCh. 19 - Prob. 39QAPCh. 19 - Prob. 40QAPCh. 19 - Give the number of unpaired electrons in...Ch. 19 - Prob. 42QAPCh. 19 - Ti(NH3)63+ has a d-orbital electron transition at...Ch. 19 - has a crystal field splitting energy, o, of...Ch. 19 - Prob. 45QAPCh. 19 - Prob. 46QAPCh. 19 - Prob. 47QAPCh. 19 - Prob. 48QAPCh. 19 - Prob. 49QAPCh. 19 - Indicate whether each of the following is true or...Ch. 19 - A child eats 10.0 g of paint containing 5.0% Pb....Ch. 19 - A certain coordination compound has the simplest...Ch. 19 - Prob. 53QAPCh. 19 - In the [Ti(H2O)63+] ion, the splitting between the...
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