Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 19, Problem 27QAP
Which of the following octahedral complexes show geometric isomerism? If geometric isomers are possible, draw their structures.
(a) [Co(en)Cl4-]
(b) [Ni(C2O4)2ClBr4-]
(c) [Cd(NH3)2Cl42-]
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Which of the following complexes has an optical isomer?(a) Tetrahedral [CdBr2Cl2]2- (b) Octahedral [CoCl4(en)]2-(c) Octahedral [Co(NH3)4Cl2]2+ (d) Tetrahedral[Co(NH3)BrClI]-
What type of isomerism is shown by the complex [Cr(H20)6]Cl3?
(ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if Δ0 > P.
(iii) Write the hybridization and shape of [CoF6]3-.
(Atomic number of Co = 27)
What type of isomerism is shown by [CO(NH3)5ONO]Cl2?
(ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if A0 < P.
(iii) Write the hybridization and shape of [Fe(CN)6]3-. (Atomic number of Fe — 26)
Chapter 19 Solutions
Chemistry: Principles and Reactions
Ch. 19 - Prob. 1QAPCh. 19 - Prob. 2QAPCh. 19 - Prob. 3QAPCh. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAPCh. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAPCh. 19 - Prob. 8QAPCh. 19 - Prob. 9QAPCh. 19 - Prob. 10QAP
Ch. 19 - Prob. 11QAPCh. 19 - Prob. 12QAPCh. 19 - What is the mass percent of sulfur in the...Ch. 19 - Prob. 14QAPCh. 19 - There are four iron atoms in each hemoglobin...Ch. 19 - Vitamin B12 is a coordination compound with cobalt...Ch. 19 - Prob. 17QAPCh. 19 - Prob. 18QAPCh. 19 - Name the following ions or compounds (a)...Ch. 19 - Name the following ions or compounds (a)...Ch. 19 - Prob. 21QAPCh. 19 - Prob. 22QAPCh. 19 - Sketch the geometry of (a)...Ch. 19 - Sketch the geometry of (a) tans-[Cu(Br)2(H2O)4]...Ch. 19 - Prob. 25QAPCh. 19 - Prob. 26QAPCh. 19 - Which of the following octahedral complexes show...Ch. 19 - Prob. 28QAPCh. 19 - Prob. 29QAPCh. 19 - Prob. 30QAPCh. 19 - Prob. 31QAPCh. 19 - Prob. 32QAPCh. 19 - Write an abbreviated orbital diagram and determine...Ch. 19 - Prob. 34QAPCh. 19 - Give the electron distribution in low-spin and/or...Ch. 19 - Prob. 36QAPCh. 19 - Prob. 37QAPCh. 19 - Prob. 38QAPCh. 19 - Prob. 39QAPCh. 19 - Prob. 40QAPCh. 19 - Give the number of unpaired electrons in...Ch. 19 - Prob. 42QAPCh. 19 - Ti(NH3)63+ has a d-orbital electron transition at...Ch. 19 - has a crystal field splitting energy, o, of...Ch. 19 - Prob. 45QAPCh. 19 - Prob. 46QAPCh. 19 - Prob. 47QAPCh. 19 - Prob. 48QAPCh. 19 - Prob. 49QAPCh. 19 - Indicate whether each of the following is true or...Ch. 19 - A child eats 10.0 g of paint containing 5.0% Pb....Ch. 19 - A certain coordination compound has the simplest...Ch. 19 - Prob. 53QAPCh. 19 - In the [Ti(H2O)63+] ion, the splitting between the...
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- Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forwardFor each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8arrow_forwardDetermine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, determine how many there are. (a) octahedral [Fe(o-phen)2Cl2]+.arrow_forward
- Iron(III) forms octahedral complexes. Sketch the structures of all the distinct isomers of [Fe(en)2Cl2]+, indicating which pairs of structures are mirror images of each other.arrow_forwardDraw the energy diagram for d-orbital electron configuration in the octahedral field for each of the following complex ions. Indicate whether the ion is paramagnetic or diamagnetic: (a) [Cr(H2O)6]3+ (H2O is a weak-field ligand) (b) [Cr(NH3)6]3+ (NH3 is a strong-field ligand) (c) [CoF6]3– (F– is a weak-field ligand) (d) [Co(CN)6]3– (CN– is a strong-field ligand) (e) [Ni(H2O)6]2+ (H2O is a weak-field ligand) (f) [Ni(en)3]2+ (en is a strong-field ligand)arrow_forwardDetermine the coordination number (c.n.) and the oxidation state (o.s.) of the transition metal in each of the following compounds or complex ions. (a) [Ti(H2O)6]3+ :(b) K4[Fe(CN)6] :(c) [Ni(H2O)2(en)2]SO4 : (d) Na[Cr(OH)4 :(e) [Co(en)2(NO2)]+ :arrow_forward
- b) Draw the structure of each of the following complexes. Clearly show the stereocentre of central metal ion. Where multiple geometric isomers are possible, draw both. (i) [Fe(SCN)4(H2O)2]²- (ii) [Co(en)2Cl2]CI (iii) [Ni(NH3)4(C2O4)2]. H2Oarrow_forwardWrite the hybridization and shape of the following complexes: (i) [CoF6]3- (ii) [Ni(CN)4]2- (Atomic number : Co = 27, Ni = 28) (b) Out of NH3 and CO, which ligand forms a more stable complex with a transition metal and why?arrow_forwardSketch the following complexes. If more than one enantiomer exists, sketch just one.(a) mer-Cr(NH3)3(Cl)3 (b) cis-[Fe(H2O)4(CN)2]Cl (c) trans-[Ni(en)2Cl2] (d) fac-Co(NH3)3(CN)3arrow_forward
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