EBK ESSENTIAL ORGANIC CHEMISTRY

3rd Edition

ISBN: 8220100659461

Author: Bruice

Publisher: PEARSON

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NMR stands for Nuclear Magnetic Resonance in which the study of different molecules is done based on the interaction of radiofrequency electromagnetic radiations with the nuclei of molecules placed in a strong magnetic field. A precise study of spectra o…

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Textbook Question

Chapter 19, Problem 45P

UDP-galactose-4-epimerase converts UDP-galactose to UDP-glucose. The reaction requires NAD⁺ as a coenzyme.

a. Propose a mechanism for the reaction.
b. Why is the enzyme called an epimerase?

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Chapter 19, Problem 44P

Chapter 19, Problem 46P

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Is this an intramolecular reaction or an intermolecular reaction?

Chapter 19 Solutions

EBK ESSENTIAL ORGANIC CHEMISTRY

Ch. 19.4 - Prob. 1P Ch. 19.4 - How many molecules of NADH are formed from the...Ch. 19.4 - Why does the OH group add to the -carbon rather...Ch. 19.5 - Prob. 4P Ch. 19.5 - Prob. 5P Ch. 19.5 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 19.5 - Prob. 7P Ch. 19.6 - Prob. 8P Ch. 19.6 - Prob. 9P Ch. 19.6 - Propose a mechanism for the reduction of...

Ch. 19.7 - Prob. 11P Ch. 19.8 - Acid-catalyzed dehydration reactions are normally...Ch. 19.8 - Prob. 13P Ch. 19.8 - Prob. 14P Ch. 19.8 - Prob. 15P Ch. 19.9 - Prob. 16P Ch. 19.10 - a. What is the name of the enzyme that converts...Ch. 19.13 - Prob. 18P Ch. 19 - Prob. 19P Ch. 19 - Prob. 20P Ch. 19 - Prob. 21P Ch. 19 - Prob. 22P Ch. 19 - Prob. 23P Ch. 19 - Prob. 24P Ch. 19 - Prob. 25P Ch. 19 - Prob. 26P Ch. 19 - Prob. 27P Ch. 19 - Prob. 28P Ch. 19 - Prob. 29P Ch. 19 - Prob. 30P Ch. 19 - Prob. 31P Ch. 19 - Prob. 32P Ch. 19 - Prob. 33P Ch. 19 - Prob. 34P Ch. 19 - Prob. 35P Ch. 19 - Prob. 36P Ch. 19 - Prob. 37P Ch. 19 - Prob. 38P Ch. 19 - Prob. 39P Ch. 19 - Prob. 40P Ch. 19 - Prob. 41P Ch. 19 - Prob. 42P Ch. 19 - Prob. 43P Ch. 19 - Prob. 44P Ch. 19 - UDP-galactose-4-epimerase converts UDP-galactose...Ch. 19 - A student is trying to determine the mechanism for...Ch. 19 - What would be the results of the experiment in...

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UDP-galactose-4-epimerase converts UDP-galactose to UDP-glucose. The reaction requires NAD + as a coenzyme. a. Propose a mechanism for the reaction. b. Why is the enzyme called an epimerase?

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Chapter 19 Solutions