Organic Chemistry
Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
Question
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Chapter 19, Problem 44PP

(a)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

(b)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

 (c)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

(d)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

(e)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

(f)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

(g)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

(h)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

(i)

Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular structure.

Concept introduction:

The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.

IUPAC Nomenclature Method

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...

For alkynes molecules, suffix will be ‘yne’.

For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol

Root word represents the longest continuous carbon skeleton of the organic molecule.

Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.

To identify: The systematic structure for the given molecule

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Chapter 19 Solutions

Organic Chemistry

Ch. 19.5 - Prob. 9ATSCh. 19.5 - Prob. 10CCCh. 19.5 - Prob. 11CCCh. 19.5 - Prob. 12CCCh. 19.5 - Prob. 13CCCh. 19.6 - Prob. 3LTSCh. 19.6 - Prob. 14PTSCh. 19.6 - Prob. 15PTSCh. 19.6 - Prob. 16ATSCh. 19.6 - Prob. 17CCCh. 19.6 - Prob. 18CCCh. 19.6 - Prob. 20PTSCh. 19.6 - Prob. 21ATSCh. 19.6 - Prob. 22CCCh. 19.7 - Prob. 5LTSCh. 19.7 - Prob. 23PTSCh. 19.7 - Prob. 24ATSCh. 19.7 - Prob. 25CCCh. 19.8 - Prob. 26CCCh. 19.8 - Prob. 27CCCh. 19.9 - Prob. 28CCCh. 19.9 - Prob. 29CCCh. 19.10 - Prob. 30CCCh. 19.10 - Prob. 31CCCh. 19.10 - Prob. 32CCCh. 19.10 - Prob. 33CCCh. 19.10 - Prob. 6LTSCh. 19.10 - Prob. 34PTSCh. 19.10 - Prob. 35PTSCh. 19.10 - Prob. 36ATSCh. 19.10 - Prob. 37ATSCh. 19.10 - Prob. 38CCCh. 19.11 - Prob. 39CCCh. 19.12 - Prob. 7LTSCh. 19.12 - Prob. 40PTSCh. 19.12 - Prob. 41ATSCh. 19.13 - Prob. 42CCCh. 19 - Prob. 43PPCh. 19 - Prob. 44PPCh. 19 - Prob. 45PPCh. 19 - Prob. 46PPCh. 19 - Prob. 47PPCh. 19 - Prob. 48PPCh. 19 - Prob. 49PPCh. 19 - Prob. 50PPCh. 19 - Prob. 51PPCh. 19 - Prob. 52PPCh. 19 - Prob. 53PPCh. 19 - Prob. 54PPCh. 19 - Prob. 55PPCh. 19 - Prob. 56PPCh. 19 - Prob. 57PPCh. 19 - Prob. 58PPCh. 19 - Prob. 59PPCh. 19 - Prob. 60PPCh. 19 - Predict the major product(s) obtained when each of...Ch. 19 - Prob. 62PPCh. 19 - Prob. 63PPCh. 19 - Prob. 64PPCh. 19 - Prob. 65PPCh. 19 - Prob. 66PPCh. 19 - Prob. 67PPCh. 19 - Prob. 68PPCh. 19 - Prob. 69PPCh. 19 - Prob. 70PPCh. 19 - Prob. 71PPCh. 19 - Prob. 72PPCh. 19 - Prob. 73PPCh. 19 - Prob. 74IPCh. 19 - Prob. 75IPCh. 19 - Prob. 76IPCh. 19 - Prob. 77IPCh. 19 - Prob. 78IPCh. 19 - Prob. 79IPCh. 19 - Prob. 80IPCh. 19 - Prob. 81IPCh. 19 - Prob. 83IPCh. 19 - Prob. 84IPCh. 19 - Prob. 85IPCh. 19 - Prob. 86IPCh. 19 - Prob. 87IPCh. 19 - Prob. 88IPCh. 19 - Prob. 89IPCh. 19 - Prob. 90IPCh. 19 - Prob. 91IPCh. 19 - Prob. 92IPCh. 19 - Prob. 93IPCh. 19 - Prob. 94CPCh. 19 - Prob. 95CPCh. 19 - Treatment of the following ketone with LiAIHa...
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