Foundations of College Chemistry, Binder Ready Version
15th Edition
ISBN: 9781119083900
Author: Morris Hein, Susan Arena, Cary Willard
Publisher: WILEY
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Chapter 19, Problem 31RQ
Interpretation Introduction
Interpretation:
In
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
198.0
200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 19 Solutions
Foundations of College Chemistry, Binder Ready Version
Ch. 19.2 - Prob. 19.1PCh. 19.3 - Prob. 19.2PCh. 19.3 - Prob. 19.3PCh. 19.3 - Prob. 19.4PCh. 19.4 - Prob. 19.5PCh. 19.5 - Prob. 19.6PCh. 19.6 - Prob. 19.7PCh. 19.7 - Prob. 19.8PCh. 19.8 - Prob. 19.9PCh. 19.9 - Prob. 19.10P
Ch. 19.10 - Prob. 19.11PCh. 19.11 - Prob. 19.12PCh. 19.12 - Prob. 19.13PCh. 19 - Prob. 1RQCh. 19 - Prob. 2RQCh. 19 - Prob. 3RQCh. 19 - Prob. 4RQCh. 19 - Prob. 5RQCh. 19 - Prob. 6RQCh. 19 - Prob. 7RQCh. 19 - Prob. 8RQCh. 19 - Prob. 9RQCh. 19 - Prob. 10RQCh. 19 - Prob. 11RQCh. 19 - Prob. 12RQCh. 19 - Prob. 13RQCh. 19 - Prob. 14RQCh. 19 - Prob. 15RQCh. 19 - Prob. 16RQCh. 19 - Prob. 17RQCh. 19 - Prob. 18RQCh. 19 - Prob. 19RQCh. 19 - Prob. 20RQCh. 19 - Prob. 21RQCh. 19 - Prob. 23RQCh. 19 - Prob. 24RQCh. 19 - Prob. 25RQCh. 19 - Prob. 26RQCh. 19 - Prob. 27RQCh. 19 - Prob. 28RQCh. 19 - Prob. 29RQCh. 19 - Prob. 30RQCh. 19 - Prob. 31RQCh. 19 - Prob. 32RQCh. 19 - Prob. 33RQCh. 19 - Prob. 34RQCh. 19 - Prob. 35RQCh. 19 - Prob. 36RQCh. 19 - Prob. 37RQCh. 19 - Prob. 1PECh. 19 - Prob. 2PECh. 19 - Prob. 3PECh. 19 - Prob. 4PECh. 19 - Prob. 5PECh. 19 - Prob. 6PECh. 19 - Prob. 7PECh. 19 - Prob. 8PECh. 19 - Prob. 9PECh. 19 - Prob. 10PECh. 19 - Prob. 11PECh. 19 - Prob. 12PECh. 19 - Prob. 13PECh. 19 - Prob. 14PECh. 19 - Prob. 15PECh. 19 - Prob. 16PECh. 19 - Prob. 17PECh. 19 - Prob. 18PECh. 19 - Prob. 19PECh. 19 - Prob. 20PECh. 19 - Prob. 21PECh. 19 - Prob. 22PECh. 19 - Prob. 23PECh. 19 - Prob. 24PECh. 19 - Prob. 25PECh. 19 - Prob. 26PECh. 19 - Prob. 27PECh. 19 - Prob. 28PECh. 19 - Prob. 29PECh. 19 - Prob. 30PECh. 19 - Prob. 31PECh. 19 - Prob. 32PECh. 19 - Prob. 33PECh. 19 - Prob. 34PECh. 19 - Prob. 35PECh. 19 - Prob. 36PECh. 19 - Prob. 37PECh. 19 - Prob. 38PECh. 19 - Prob. 39PECh. 19 - Prob. 40PECh. 19 - Prob. 41PECh. 19 - Prob. 42PECh. 19 - Prob. 43PECh. 19 - Prob. 44PECh. 19 - Prob. 45PECh. 19 - Prob. 46PECh. 19 - Prob. 47PECh. 19 - Prob. 48PECh. 19 - Prob. 49PECh. 19 - Prob. 50PECh. 19 - Prob. 51PECh. 19 - Prob. 52PECh. 19 - Prob. 53PECh. 19 - Prob. 54PECh. 19 - Prob. 55PECh. 19 - Prob. 56PECh. 19 - Prob. 57PECh. 19 - Prob. 58PECh. 19 - Prob. 59PECh. 19 - Prob. 60PECh. 19 - Prob. 61PECh. 19 - Prob. 62PECh. 19 - Prob. 63PECh. 19 - Prob. 64PECh. 19 - Prob. 65AECh. 19 - Prob. 66AECh. 19 - Prob. 67AECh. 19 - Prob. 68AECh. 19 - Prob. 69AECh. 19 - Prob. 70AECh. 19 - Prob. 71AECh. 19 - Prob. 72AECh. 19 - Prob. 73AECh. 19 - Prob. 74AECh. 19 - Prob. 75AECh. 19 - Prob. 76AECh. 19 - Prob. 77AECh. 19 - Prob. 78AECh. 19 - Prob. 79AECh. 19 - Prob. 80AECh. 19 - Prob. 81AECh. 19 - Prob. 82AECh. 19 - Prob. 83AECh. 19 - Prob. 84AECh. 19 - Prob. 85AECh. 19 - Prob. 86AECh. 19 - Prob. 87AECh. 19 - Prob. 89AECh. 19 - Prob. 90AE
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
- Label the spectrum with spectroscopyarrow_forwardQ1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forwardLabel the spectrumarrow_forward
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