Given the following half-reactions and E o values, M n 3 + ( a q ) + e − → M n 2 + ( a q ) E o = 1.54 V M n O 2 ( s ) + 4 H + ( a q ) + e − → M n 3 + ( a q ) + 2 H 2 O ( l ) E o = 0.95 V write a balanced equation for the formation of M n 2 + and MnO 2 from M n 3 + , and calculate the value of E o for this reaction. Is the reaction spontaneous under standard-state conditions?
Given the following half-reactions and E o values, M n 3 + ( a q ) + e − → M n 2 + ( a q ) E o = 1.54 V M n O 2 ( s ) + 4 H + ( a q ) + e − → M n 3 + ( a q ) + 2 H 2 O ( l ) E o = 0.95 V write a balanced equation for the formation of M n 2 + and MnO 2 from M n 3 + , and calculate the value of E o for this reaction. Is the reaction spontaneous under standard-state conditions?
Solution Summary: The author explains that the balanced equation for the overall cell reaction and the value of E° of the reaction under standard state conditions needs to be determined.
Given the following half-reactions and Eo values,
M
n
3
+
(
a
q
)
+
e
−
→
M
n
2
+
(
a
q
)
E
o
=
1.54
V
M
n
O
2
(
s
)
+
4
H
+
(
a
q
)
+
e
−
→
M
n
3
+
(
a
q
)
+
2
H
2
O
(
l
)
E
o
=
0.95
V
write a balanced equation for the formation of
M
n
2
+
and MnO2 from
M
n
3
+
, and calculate the value of
E
o
for this reaction. Is the reaction spontaneous under standard-state conditions?
Part 2 (0.5 point)
0-
Draw the major organic product with the correct geometry.
10
1:
70000 х
く
1st attempt
Part 1 (0.5 point) Feedback
Please draw all four bonds at chiral centers.
P
See Periodic Table See Hint
Heating an alcohol in the presence of sulfuric or phosphoric acid will cause a dehydration to occur: the removal of the elements of water from a
molecule, forming an alkene. The reaction usually follows an E1 mechanism. The SN1 pathway is suppressed by using a strong acid whose conjugate
base is a poor nucleophile. Further, heating the reaction mixture causes a greater increase in the rate of E1 compared to the rate of S№1.
2nd attempt
0
See Periodic Table
See Hint
Draw the organic intermediate from the first step (no byproducts) and draw curved arrow(s) to show how it reacts.
TH
+11:
1st attempt
Feedback
H
H
H
C
F
F
See Periodic Table
See Hint
This molecule undergoes an E1 mechanism when stirred in methanol.
3rd attempt
CH₂OH
CH₂OH
6148
O
See Periodic Table. See Hint
Draw 3 chemical species including formal charges and lone pairs of electrons. Add the missing curved arrow notation.
H
N
O O SA 3
Br
I
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell