LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
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Chapter 19, Problem 19.142SP
Interpretation Introduction
Interpretation:
Metal ion should be identified after the
Concept introduction:
During the electrolysis, the amount of substance that is produced at an electrode of cell depends on the amount of charge passed through it. The current can be calculated as follows:
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 19 Solutions
LCPO CHEMISTRY W/MODIFIED MASTERING
Ch. 19 - Balance the following net ionic equation by the...Ch. 19 - Balance the following net ionic equation by the...Ch. 19 - Prob. 19.3PCh. 19 - Balance the following net ionic equation by the...Ch. 19 - Prob. 19.5PCh. 19 - Prob. 19.6ACh. 19 - PRACTICE 18.7 Write a balanced equation for the...Ch. 19 - Consider the following galvanic cell with...Ch. 19 - The standard cell potential at 25oC is 1.20 V for...Ch. 19 - The standard free-energy change is 59.8kJ for the...
Ch. 19 - Which substance is the strongest reducting agent:...Ch. 19 - Consider the following table of standard reduction...Ch. 19 - Use Table 19.1 to calculate the value of Eo for...Ch. 19 - Prob. 19.14ACh. 19 - Prob. 19.15PCh. 19 - Prob. 19.16ACh. 19 - Consider a galvanic cell that uses the reaction...Ch. 19 - Accidentally chewing on a stray fragment of...Ch. 19 - Consider the following galvanic cell: What is the...Ch. 19 - Prob. 19.20ACh. 19 - What is the pH of the solution in the anode...Ch. 19 - Prob. 19.22ACh. 19 - Use the data in Table 19.1 to calculate the...Ch. 19 - Prob. 19.24ACh. 19 - Prob. 19.25PCh. 19 - Prob. 19.26ACh. 19 - In what ways are fuel cells and batteries similar,...Ch. 19 - Prob. 19.28PCh. 19 - The cell reaction in a hydrogen—oxygen fuel cell...Ch. 19 - Prob. 19.30PCh. 19 - Prob. 19.31PCh. 19 - A steam—hydrocarbon reforming process is one...Ch. 19 - Another method of hydrogen production is the...Ch. 19 - The following picture of a galvanic cell has lead...Ch. 19 - Prob. 19.35CPCh. 19 - Prob. 19.36CPCh. 19 - Prob. 19.37CPCh. 19 - Sketch a cell with inert electrodes suitable for...Ch. 19 - Prob. 19.39CPCh. 19 - Prob. 19.40CPCh. 19 - Consider the following galvanic cell with 0.10 M...Ch. 19 - Classify each of the following unbalanced...Ch. 19 - Classify each of the following unbalanced...Ch. 19 - Prob. 19.44SPCh. 19 - Prob. 19.45SPCh. 19 - Write unbalanced oxidation and reduction...Ch. 19 - Prob. 19.47SPCh. 19 - Balance the following half-reactions. (acidic)...Ch. 19 - Prob. 19.49SPCh. 19 - Write balanced net ionic equations for the...Ch. 19 - Write balanced net ionic equations for the...Ch. 19 - Write balanced net ionic equations for the...Ch. 19 - Prob. 19.53SPCh. 19 - Why is the cathode of a galvanic cell considered...Ch. 19 - What is the function of a salt bridge in a...Ch. 19 - Describe galvanic cells that use the following...Ch. 19 - Prob. 19.57SPCh. 19 - Write a balanced equation for the overall cell...Ch. 19 - Write the shorthand notation for a galvanic cell...Ch. 19 - Write the standard shorthand notation for a...Ch. 19 - Write the standard shorthand notation for a...Ch. 19 - An H2/H+ half-cell (anode) and an Ag+/Ag half-cell...Ch. 19 - A galvanic cell is constructed from a Zn/Zn2+...Ch. 19 - Write balanced equations for the electrode and...Ch. 19 - Prob. 19.65SPCh. 19 - What conditions must be met for a cell potential E...Ch. 19 - How are standard reduction potentials defined?Ch. 19 - The silver oxide-zinc battery used in watches...Ch. 19 - The standard cell potential for a lead storage...Ch. 19 - What is the value of x for the following reaction...Ch. 19 - Prob. 19.71SPCh. 19 - Use the standard free energies of formation in...Ch. 19 - Prob. 19.73SPCh. 19 - Arrange the following oxidizing agents in order of...Ch. 19 - Prob. 19.75SPCh. 19 - Consider the following substances:...Ch. 19 - Prob. 19.77SPCh. 19 - Consider the following substances:...Ch. 19 - Prob. 19.79SPCh. 19 - Use the data in Appendix D to predict whether the...Ch. 19 - Prob. 19.81SPCh. 19 - Prob. 19.82SPCh. 19 - What reaction can occur, if any, when the...Ch. 19 - The standard potential for the following galvanic...Ch. 19 - The following reaction has an Eo value of 0.27 V:...Ch. 19 - Prob. 19.86SPCh. 19 - Prob. 19.87SPCh. 19 - Prob. 19.88SPCh. 19 - Calculate Eo and Go (in kilojoules) for the...Ch. 19 - Calculate Eo for each of the following reactions,...Ch. 19 - Calculate Eo for each of the following reactions,...Ch. 19 - Consider a galvanic cell that uses the following...Ch. 19 - Given the following half-reactions and Eo values,...Ch. 19 - Consider a galvanic cell that uses the reaction...Ch. 19 - Consider a galvanic cell based on the reaction...Ch. 19 - Prob. 19.96SPCh. 19 - Prob. 19.97SPCh. 19 - What is the Zn2+:Cu2+ concentration ratio in the...Ch. 19 - What is the Fe2+:Sn2+ concentration ratio in the...Ch. 19 - The Nernst equation applies to both cell reactions...Ch. 19 - When suspected drunk drivers are tested with a...Ch. 19 - What is the reduction potential at 25o C for the...Ch. 19 - At one time on Earth, iron was present mostly as...Ch. 19 - Standard reduction potentials for the Pb2+/Pb and...Ch. 19 - Prob. 19.105SPCh. 19 - Prob. 19.106SPCh. 19 - Prob. 19.107SPCh. 19 - Prob. 19.108SPCh. 19 - Prob. 19.109SPCh. 19 - Use the data in Table 19.1 to calculate the...Ch. 19 - From standard reduction potentials, calculate the...Ch. 19 - Calculate the equilibrium constant at 25 oC for...Ch. 19 - Calculate the equilibrium constant at 25 oC for...Ch. 19 - Prob. 19.114SPCh. 19 - Prob. 19.115SPCh. 19 - Prob. 19.116SPCh. 19 - Prob. 19.117SPCh. 19 - Write a balanced equation for the overall cell...Ch. 19 - Prob. 19.119SPCh. 19 - You are on your dream vacation at the beach when a...Ch. 19 - A storm has knocked out power to your beach house,...Ch. 19 - For a lead storage battery: (a) Sketch one cell...Ch. 19 - A mercury battery uses the following electrode...Ch. 19 - Prob. 19.124SPCh. 19 - Prob. 19.125SPCh. 19 - Prob. 19.126SPCh. 19 - Prob. 19.127SPCh. 19 - Prob. 19.128SPCh. 19 - Prob. 19.129SPCh. 19 - Prob. 19.130SPCh. 19 - If the metal zinc were not available for the...Ch. 19 - Prob. 19.132SPCh. 19 - Prob. 19.133SPCh. 19 - Prob. 19.134SPCh. 19 - Prob. 19.135SPCh. 19 - Prob. 19.136SPCh. 19 - Predict the anode, cathode, and overall cell...Ch. 19 - Prob. 19.138SPCh. 19 - Prob. 19.139SPCh. 19 - Prob. 19.140SPCh. 19 - Prob. 19.141SPCh. 19 - Prob. 19.142SPCh. 19 - What is the metal ion in a metal nitrate solution...Ch. 19 - Prob. 19.144SPCh. 19 - Prob. 19.145SPCh. 19 - Prob. 19.146SPCh. 19 - Prob. 19.147SPCh. 19 - Consider the following half-reactions and Eo...Ch. 19 - Consider a galvanic cell that uses the following...Ch. 19 - Prob. 19.150MPCh. 19 - Prob. 19.151MPCh. 19 - Prob. 19.152MPCh. 19 - Prob. 19.153MPCh. 19 - Prob. 19.154MPCh. 19 - The reaction of MnO4- with oxalic acid (H2C2O4) in...Ch. 19 - Calculate the standard reduction potential for...Ch. 19 - Prob. 19.157MPCh. 19 - Prob. 19.158MPCh. 19 - Consider a galvanic cell that utilizes the...Ch. 19 - Prob. 19.160MPCh. 19 - Prob. 19.161MPCh. 19 - Prob. 19.162MPCh. 19 - Prob. 19.163MPCh. 19 - Consider the redox titration of 100.0 mL of a...
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