The block diagram structures for all possible products of the partial hydrogenation of the given molecule with two H 2 molecules have to be drawn. Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids. The process of addition of hydrogen atoms across the carbon-carbon double or triple bond is known as hydrogenation. Hydrogenation is the process of converting an unsaturated compound into a saturated compound.
The block diagram structures for all possible products of the partial hydrogenation of the given molecule with two H 2 molecules have to be drawn. Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids. The process of addition of hydrogen atoms across the carbon-carbon double or triple bond is known as hydrogenation. Hydrogenation is the process of converting an unsaturated compound into a saturated compound.
Solution Summary: The author illustrates the partial hydrogenation of a given molecule with two H_ 2 molecules.
Interpretation: The block diagram structures for all possible products of the partial hydrogenation of the given molecule with two H2 molecules have to be drawn.
Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.
The process of addition of hydrogen atoms across the carbon-carbon double or triple bond is known as hydrogenation. Hydrogenation is the process of converting an unsaturated compound into a saturated compound.
(b)
Interpretation Introduction
Interpretation: The block diagram structures for all possible products of the partial hydrogenation of the given molecule with two H2 molecules have to be drawn.
Concept introduction: Triacylglycerol is produced by the reaction of one molecule of glycerol and three molecules of fatty acid. The three hydroxyl groups of glycerol get esterified on reaction with fatty acids.
The process of addition of hydrogen atoms across the carbon-carbon double or triple bond is known as hydrogenation. Hydrogenation is the process of converting an unsaturated compound into a saturated compound.
Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
Chapter 19 Solutions
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