(a) Interpretation: The structure corresponding to N-methylaniline is to be drawn. Concept Introduction: Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as- Primary amines ( RNH 2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group. Secondary amines ( R 2 NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups. Tertiary amine ( R 3 N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 1

Question

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below: QUESTION: Summarise and report these results including an indication of measurement uncertainty. In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical). Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…

Indicate the rate expressions for reactions that have order 0, 1, and 2.

Answer 2

Question

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 3

Question

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 4

Question

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 5

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 6

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 7

Chapter 18.2, Problem 18.6P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to N-methylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to m-Ethylaniline is to be drawn.

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to 3,5-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N,N-diethylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.1 - Prob. 18.3P Ch. 18.1 - Prob. 18.4P Ch. 18.2 - Prob. 18.5P Ch. 18.2 - Prob. 18.6P Ch. 18.2 - Prob. 18.7P Ch. 18.3 - Prob. 18.8P Ch. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.10P

Solution Summary: The author explains the structure corresponding to N-methylaniline and m-Ethylaniline.

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Chapter 18 Solutions