Concept explainers
(a)
Interpretation:
The structure of cyclobutylamine needs to be determined.
Concept Introduction:
The name of the
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(b)
Interpretation:
The structure of4-nonanamine needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(c)
Interpretation:
The structure of N-pentylaniline needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(d)
Interpretation:
The structure of3-amino-2-butanone needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(e)
Interpretation:
The structure of3-methyl-1-butanamine needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(f)
Interpretation:
The structure of N-ethyl-N-propylcyclopentylamine needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
Want to see the full answer?
Check out a sample textbook solution
Chapter 18 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
- Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forwardBelow is the SN1 reaction of (S)-3-chlorocyclohexene and hydroxide (OH). Draw the missing curved arrows, lone pairs of electrons, and nonzero formal charges. In the third box, draw the two enantiomeric products that will be produced. 5th attempt Please draw all four bonds at chiral centers. Draw the two enantiomeric products that will be produced. Draw in any hydrogen at chiral centers. 1000 4th attempt Feedback Please draw all four bonds at chiral centers. 8. R5 HO: See Periodic Table See Hint H Cl Br Jid See Periodic Table See Hintarrow_forwardShow that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.arrow_forward
- (a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.arrow_forwardCan I please get help with #3 & 4? Thanks you so much!arrow_forwardA solution consisting of 0.200 mol methylbenzene, C,H,CH,, in 500. g of nitrobenzene, CH,NO₂, freezes at 3.2°C. Pure nitrobenzene freezes at 6.0°C. The molal freezing point constant of nitrobenzene is _ °C/m. a) 2.8 b) 3.2 c) 5.6 d) 7.0 e) 14.0arrow_forward
- Below is the SN1 reaction of (S)-3-chlorocyclohexene and hydroxide ("OH). Draw the missing curved arrows, lone pairs of electrons, and nonzero formal charges. In the third box, draw the two enantiomeric products that will be produced. 2nd attempt Please draw all four bonds at chiral centers. 0 D Draw the missing curved arrow notation. Add lone pairs of electrons and nonzero formal charges. + 노 V 1st attempt Feedback Please draw all four bonds at chiral centers. See Periodic Table See Hint F P 41 H Br See Periodic Table See Hint H Larrow_forwardHow close are the Mulliken and Pauling electronegativity scales? (a) Now that the ionization energies and electron affinities have been defined, calculate the Mulliken and Pauling electronegativities for C, N, O and F. Compare them. (Make the necessary adjustments to the values, such as dividing the ionization energies and electron affinities by 230kj/mol) (b) Plot both sets of electronegativities against atomic number (use the same graph). (c) Which scale depends most consistently on position in the Periodic Table?arrow_forwardBelow is the SN2 reaction between 2-bromopropane and iodide (I). Draw the mechanism arrows in the first box to reflect electron movements. In both boxes, add lone pairs of electrons and nonzero formal charges. 4th attempt Feedback 3rd attempt Feedback 1 -Br H :Bri :Br: ili See Periodic Table See Hint ini See Periodic Table See Hintarrow_forward
- When 4-chloro-1-butanol is placed in sodium hydride, a cyclization reaction occurs. 3rd attempt 2 HO NaH CI D Draw the curved arrow notation to form the intermediate. 4 2 H₂ See Periodic Table See Hint =arrow_forwardSketch, qualitatively, the potential energy curves of the N-N bond of N2H4, N2 and N3- graph. Explain why the energy at the minimum of each curve is not the same.arrow_forward(a) Show that the lattice energies are inversely proportional to the distance between ions in MX (M = alkali metal, X = halide ions) by plotting the lattice energies of KF, KCl, and KI against the internuclear distances, dMX. The lattice energies of KF, KCl, and KI are 826, 717, and 645 kJ/mol, respectively. Does the correlation obtained correlate well? You will need to use a standard graphing program to construct the graph (such as a spreadsheet program). It will generate an equation for the line and calculate a correlation coefficient. (b) Estimate the lattice energy of KBr from your graph. (c) Find an experimental value for the lattice energy of KBr in the literature, and compare this value with the one calculated in (b). Do they agree?arrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY