The structure of the carbonyl compound and the amine used to form the given imine is to be predicted. Concept introduction: The reaction between ketone / aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

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The emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Expert Solution & Answer

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Answer 5

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 6

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 7

Chapter 18.14, Problem 18.19P

(a)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imines is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 14

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 15

(e)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 16

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 17

(f)

Interpretation Introduction

Interpretation:

The structure of the carbonyl compound and the amine used to form the given imine is to be predicted.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition consists of two steps. The first step is the acid catalyzed addition of the amine to the carbonyl group. And the second step is acid catalyzed dehydration to get the desired product (an imine).

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 18.3 - Give the IUPAC name and (if possible) a common...Ch. 18.5D - NMR spectra for two compounds are given here,...Ch. 18.5D - Why were no products from the McLafferty...Ch. 18.5D - Use equations to show the fragmentation leading to...Ch. 18.5E - Prob. 18.5P Ch. 18.7D - Show how you would synthesize each compound from...Ch. 18.8 - Prob. 18.7P Ch. 18.9 - Predict the products of the following reactions....Ch. 18.9 - Show how the following transformations may be...Ch. 18.10 - Prob. 18.10P

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Chapter 18 Solutions