The mechanism of removing of tritium from compound 1 and 2 has to be given. Concept Introduction: Electrophilic substitution reaction is a type of reaction in which a particular group or atom in a compound is replaced by electrophile. An electrophile is a species that is deficient of electrons Substitution reaction is a type of organic reaction where one group that is present in the substrate is replaced by another group.

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Chapter 18, Problem 86IP

(a)

Interpretation Introduction

Interpretation: The mechanism of removing of tritium from compound 1 and 2 has to be given.

Concept Introduction:

Electrophilic substitution reaction is a type of reaction in which a particular group or atom in a compound is replaced by electrophile. An electrophile is a species that is deficient of electrons

Substitution reaction is a type of organic reaction where one group that is present in the substrate is replaced by another group.

(b)

Interpretation Introduction

Interpretation: Compound that is expected to remove tritium faster has to be predicted and explained.

Concept Introduction:

Electrophilic substitution reaction is a type of reaction in which a particular group or atom in a compound is replaced by electrophile. An electrophile is a species that is deficient of electrons

Substitution reaction is a type of organic reaction where one group that is present in the substrate is replaced by another group.

Resonance is an electron displacement effect for stabilizing a molecule through delocalization of bonding electrons in the pi orbital.

Delocalized electrons stabilize a compound. The extra stability gains from having delocalized electrons are called resonance stabilization or resonance energy.

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