The synthesis of the ketone, ( E ) - 1 , 6 -henicosadien- 11 -one using ( E ) - 5 , 10 -undecadien- 1 -ol and 1 -decanol as sources of all carbons has to be outlined. Concept introduction: Pyridinium chlorochromate is an oxidising agent which is used to stop the oxidation of the alcohols to aldehydes or ketones . Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones. Grignard reaction is a reaction in which aryl or alkyl magnesium halides react with carbonyl compounds to produce an alcohol. This reaction occurs through the addition of the alkyl substituent to the carbonyl carbon.

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Answer 1

Question

Chapter 18, Problem 39P

Interpretation Introduction

Interpretation:

The synthesis of the ketone, (E)-1,6-henicosadien-11-one using (E)-5,10-undecadien-1-ol and 1-decanol as sources of all carbons has to be outlined.

Concept introduction:

Pyridinium chlorochromate is an oxidising agent which is used to stop the oxidation of the alcohols to aldehydes or ketones. Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones.

Grignard reaction is a reaction in which aryl or alkyl magnesium halides react with carbonyl compounds to produce an alcohol. This reaction occurs through the addition of the alkyl substituent to the carbonyl carbon.

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Answer 2

Question

Chapter 18, Problem 39P

Interpretation Introduction

Interpretation:

The synthesis of the ketone, (E)-1,6-henicosadien-11-one using (E)-5,10-undecadien-1-ol and 1-decanol as sources of all carbons has to be outlined.

Concept introduction:

Pyridinium chlorochromate is an oxidising agent which is used to stop the oxidation of the alcohols to aldehydes or ketones. Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones.

Grignard reaction is a reaction in which aryl or alkyl magnesium halides react with carbonyl compounds to produce an alcohol. This reaction occurs through the addition of the alkyl substituent to the carbonyl carbon.

Expert Solution & Answer

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Answer 3

Question

Chapter 18, Problem 39P

Interpretation Introduction

Interpretation:

The synthesis of the ketone, (E)-1,6-henicosadien-11-one using (E)-5,10-undecadien-1-ol and 1-decanol as sources of all carbons has to be outlined.

Concept introduction:

Pyridinium chlorochromate is an oxidising agent which is used to stop the oxidation of the alcohols to aldehydes or ketones. Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones.

Grignard reaction is a reaction in which aryl or alkyl magnesium halides react with carbonyl compounds to produce an alcohol. This reaction occurs through the addition of the alkyl substituent to the carbonyl carbon.

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Answer 4

Question

Chapter 18, Problem 39P

Interpretation Introduction

Interpretation:

The synthesis of the ketone, (E)-1,6-henicosadien-11-one using (E)-5,10-undecadien-1-ol and 1-decanol as sources of all carbons has to be outlined.

Concept introduction:

Pyridinium chlorochromate is an oxidising agent which is used to stop the oxidation of the alcohols to aldehydes or ketones. Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones.

Grignard reaction is a reaction in which aryl or alkyl magnesium halides react with carbonyl compounds to produce an alcohol. This reaction occurs through the addition of the alkyl substituent to the carbonyl carbon.

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Answer 5

Chapter 18, Problem 39P

Interpretation Introduction

Interpretation:

The synthesis of the ketone, (E)-1,6-henicosadien-11-one using (E)-5,10-undecadien-1-ol and 1-decanol as sources of all carbons has to be outlined.

Concept introduction:

Pyridinium chlorochromate is an oxidising agent which is used to stop the oxidation of the alcohols to aldehydes or ketones. Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones.

Grignard reaction is a reaction in which aryl or alkyl magnesium halides react with carbonyl compounds to produce an alcohol. This reaction occurs through the addition of the alkyl substituent to the carbonyl carbon.

Answer 6

Chapter 18, Problem 39P

Interpretation Introduction

Interpretation:

The synthesis of the ketone, (E)-1,6-henicosadien-11-one using (E)-5,10-undecadien-1-ol and 1-decanol as sources of all carbons has to be outlined.

Concept introduction:

Pyridinium chlorochromate is an oxidising agent which is used to stop the oxidation of the alcohols to aldehydes or ketones. Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones.

Grignard reaction is a reaction in which aryl or alkyl magnesium halides react with carbonyl compounds to produce an alcohol. This reaction occurs through the addition of the alkyl substituent to the carbonyl carbon.

Answer 7

Chapter 18, Problem 39P

Interpretation Introduction

Interpretation:

The synthesis of the ketone, (E)-1,6-henicosadien-11-one using (E)-5,10-undecadien-1-ol and 1-decanol as sources of all carbons has to be outlined.

Concept introduction:

Pyridinium chlorochromate is an oxidising agent which is used to stop the oxidation of the alcohols to aldehydes or ketones. Primary alcohols on reaction with pyridinium chlorochromate produce aldehydes, while secondary alcohols give ketones.

Grignard reaction is a reaction in which aryl or alkyl magnesium halides react with carbonyl compounds to produce an alcohol. This reaction occurs through the addition of the alkyl substituent to the carbonyl carbon.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 18.1 - Prob. 1P Ch. 18.1 - Prob. 2P Ch. 18.3 - Prob. 3P Ch. 18.4 - Prob. 4P Ch. 18.4 - Prob. 5P Ch. 18.6 - Prob. 6P Ch. 18.7 - Prob. 7P Ch. 18.7 - Prob. 8P Ch. 18.7 - Prob. 9P Ch. 18.8 - Prob. 10P

Solution Summary: The author explains how the ketone is synthesised using Pyridinium chlorochromate and Grignard reaction.

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