ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 18.4, Problem 4P
Interpretation Introduction

Interpretation: It is to be identified if catalytic hydrogenation can be used to reduce a carboxylic acid to a primary alcohol in the first step of the sequence RCO2HRCH2OHRCHO.

Concept introduction: The addition of H2 to a molecule in the presence of a catalyst is known as catalytic hydrogenation reaction. This process is used to reduce aldehydes and ketones to alcohols.

Lithium aluminum hydride and sodium borohydride are strong reducing agents. They are inorganic compounds which are used as the reducing agents in organic synthesis. They used for the conversion of carboxylic acids, aldehydes and ketones into primary and secondary alcohols.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

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ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE

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