(a) Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted. Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl 3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 18, Problem 18.6P

Interpretation Introduction

(a)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(b)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(c)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 18, Problem 18.6P

Interpretation Introduction

(a)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(b)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(c)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 18, Problem 18.6P

Interpretation Introduction

(a)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(b)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(c)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 18, Problem 18.6P

Interpretation Introduction

(a)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(b)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(c)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

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Answer 5

Chapter 18, Problem 18.6P

Interpretation Introduction

(a)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(b)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Interpretation Introduction

(c)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Answer 6

Chapter 18, Problem 18.6P

Interpretation Introduction

(a)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Answer 7

Chapter 18, Problem 18.6P

Interpretation Introduction

(a)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Answer 8

Interpretation Introduction

(b)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Answer 9

Interpretation Introduction

(b)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Answer 10

Interpretation Introduction

(c)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Answer 11

Interpretation Introduction

(c)

Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.

Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which ionizes the carbon-halogen bond of the acid chloride and forms a positively charged carbon electrophile which is resonance stabilized. Then the electrophile reacts with benzene.

Answer 12

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Answer 14

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Answer 15

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Problem 18.9 Draw the product of each reaction a....Ch. 18 - Prob. 18.10P

Solution Summary: The author explains the reaction of benzene with an acid chloride to form the required ketone using a Friedel-Craft acylation.

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Chapter 18 Solutions