(a) Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn. Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

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Answer 1

Question

Chapter 18, Problem 18.11P

Interpretation Introduction

(a)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(b)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(c)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

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Label the electrophilic and nucleophilic sites in each molecule.

Draw the structure (including stereochemistry) of an alkyl chloride that forms each alkene as the exclusive E2 elimination product.

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Answer 2

Question

Chapter 18, Problem 18.11P

Interpretation Introduction

(a)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(b)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(c)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

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Answer 3

Question

Chapter 18, Problem 18.11P

Interpretation Introduction

(a)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(b)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(c)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

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Answer 4

Question

Chapter 18, Problem 18.11P

Interpretation Introduction

(a)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(b)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(c)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

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Answer 5

Chapter 18, Problem 18.11P

Interpretation Introduction

(a)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(b)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Interpretation Introduction

(c)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Answer 6

Chapter 18, Problem 18.11P

Interpretation Introduction

(a)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Answer 7

Chapter 18, Problem 18.11P

Interpretation Introduction

(a)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Answer 8

Interpretation Introduction

(b)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Answer 9

Interpretation Introduction

(b)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Answer 10

Interpretation Introduction

(c)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Answer 11

Interpretation Introduction

(c)

Interpretation: The intramolecular alkylation product formed from given reactants is to be drawn.

Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. The carbocation is generated in the presence of strong acid.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Problem 18.9 Draw the product of each reaction a....Ch. 18 - Prob. 18.10P

Solution Summary: The author explains the steps involved in the formation of intramolecular alkylation product from given reactants.

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Chapter 18 Solutions