Concept explainers
Synthesize each compound from benzene and any other organic or inorganic reagents.
a. c. e. g.
b. d. f. h.
(a)
Interpretation: The synthesis of given compound from benzene and any other organic or inorganic reagent is to be stated.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
Answer to Problem 18.63P
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown below:
Explanation of Solution
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 1.
Figure 1
The synthesis of given compound takes place by chlorination of benzene, Friedel-Craft acylation and clemmensen reduction at last step.
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 1.
(b)
Interpretation: The synthesis of given compound from benzene and any other organic or inorganic reagent is to be stated.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
Answer to Problem 18.63P
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown below:
Explanation of Solution
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 2.
Figure 2
The synthesis of given compound take place in four steps: Friedel-Craft alkylation, sulfonation, chlorination and at last oxidation.
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 2.
(c)
Interpretation: The synthesis of given compound from benzene and any other organic or inorganic reagent is to be stated.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
Answer to Problem 18.63P
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown below:
Explanation of Solution
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 3.
Figure 3
The first, second, third and fourth step involved in the synthesis of given compound is chlorination, Friedel-Craft acylation, Wittig reaction and nitration, respectively.
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 3.
(d)
Interpretation: The synthesis of given compound from benzene and any other organic or inorganic reagent is to be stated.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
Answer to Problem 18.63P
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown below:
Explanation of Solution
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 4.
Figure 4
The first step of the synthesis is Friedel-Craft alkylation reaction. The product of this reaction undergoes nitration reaction. In next step, the
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 4.
(e)
Interpretation: The synthesis of given compound from benzene and any other organic or inorganic reagent is to be stated.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
Answer to Problem 18.63P
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown below:
Explanation of Solution
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 5.
Figure 5
Benzene undergoes nitration on reaction with
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 5.
(f)
Interpretation: The synthesis of given compound from benzene and any other organic or inorganic reagent is to be stated.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
Answer to Problem 18.63P
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown below:
Explanation of Solution
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 6.
Figure 6
Benzene on Friedel-Craft alkylation with ethylchloride gives ethylbenzene. This product undergoes bromination in presence of light. The next step involves the abstraction of bromine on reaction with tertiary butoxide. This leads to the formation of
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 6.
(g)
Interpretation: The synthesis of given compound from benzene and any other organic or inorganic reagent is to be stated.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
Answer to Problem 18.63P
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown below:
Explanation of Solution
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 7.
Figure 7
The first two steps involved in the synthesis of given compound are Friedel-Craft alkylation followed by chlorination in the presence of light. The chlorine group is replaced by hydroxyl group on reaction with
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 7.
(h)
Interpretation: The synthesis of given compound from benzene and any other organic or inorganic reagent is to be stated.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.
Answer to Problem 18.63P
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown below:
Explanation of Solution
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 8.
Figure 8
Benzene on Friedel-Craft alkylation with ethylchloride gives ethylbenzene. This product undergoes bromination in presence of light. The next step involves the abstraction of bromine on reaction with tertiary butoxide. This leads to the formation of
The synthesis of given compound from benzene and any other organic or inorganic reagent is shown in Figure 8.
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Chapter 18 Solutions
ORGANIC CHEMISTRY
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- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning