University Physics with Modern Physics (14th Edition)
14th Edition
ISBN: 9780321973610
Author: Hugh D. Young, Roger A. Freedman
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 18, Problem 18.69P
(a)
To determine
Plot the graph of
(b)
To determine
Show the locations of points on graph of
(c)
To determine
The values of
(d)
To determine
The work that has to be done to pull the molecules at
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The potential energy of two atoms in a diatomic molecule is approximated by U(r) = a/r12-b/r6, where r is the spacing between atoms and a and b are positive constants.
Suppose the distance between the two atoms is equal to the equilibrium distance found in part A. What minimum energy must be added to the molecule to dissociate it -
that is, to separate the two atoms to an infinite distance apart? This is called the dissociation energy of the molecule. Express your answer in terms of the variables a and b.
For the molecule CO, the equilibrium distance between the carbon and oxygen atoms is 1.13\times 10-10m and the dissociation energy is 1.54\times 10-18J per
molecule. Find the value of the constant a. Express your answer in joules times meter in the twelth power. Find the value of the constant b. Express your answer in joules
times meter in the sixth power.
One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. Find, in terms of A and B, (a) the value r0 at which the energy is a minimum and (b) the energy E required to break up a diatomic molecule.
Q3: The potential energy function for the force between two atoms in
a diatomic molecule is approximately given by
U(x) = -
읆 옮
, where a and b are constant and x is the distance between the atoms. If the
dissociation energy of the molecule is (U(x= ∞) -U at equilibrium), D is
(a) b²/6a
(b) b²/2a
(c) b²/12a
(d) b²/4a
Chapter 18 Solutions
University Physics with Modern Physics (14th Edition)
Ch. 18.1 - Rank the following ideal gases in order from...Ch. 18.2 - Prob. 18.2TYUCh. 18.3 - Rank the following gases in order from (a) highest...Ch. 18.4 - A cylinder with a fixed volume contains hydrogen...Ch. 18.5 - A quantity of gas containing N molecules has a...Ch. 18.6 - The average atmospheric pressure on Mars is 6.0 ...Ch. 18 - Section 18.1 states that ordinarily, pressure,...Ch. 18 - In the ideal-gas equation, could an equivalent...Ch. 18 - When a car is driven some distance, the air...Ch. 18 - The coolant in an automobile radiator is kept at a...
Ch. 18 - Unwrapped food placed in a freezer experiences...Ch. 18 - A group of students drove from their university...Ch. 18 - The derivation of the ideal-gas equation included...Ch. 18 - A rigid, perfectly insulated container has a...Ch. 18 - (a) Which has more atoms: a kilogram of hydrogen...Ch. 18 - Use the concepts of the kinetic-molecular model to...Ch. 18 - The proportions of various gases in the earths...Ch. 18 - Comment on the following statement: When two gases...Ch. 18 - Prob. 18.13DQCh. 18 - The temperature of an ideal gas is directly...Ch. 18 - If the pressure of an ideal monatomic gas is...Ch. 18 - In deriving the ideal-gas equation from the...Ch. 18 - Imagine a special air filter placed in a window of...Ch. 18 - Prob. 18.18DQCh. 18 - Consider two specimens of ideal gas at the same...Ch. 18 - The temperature of an ideal monatomic gas is...Ch. 18 - Prob. 18.21DQCh. 18 - (a) If you apply the same amount of heat to 1.00...Ch. 18 - Prob. 18.23DQCh. 18 - In a gas that contains N molecules, is it accurate...Ch. 18 - The atmosphere of the planet Mars is 95.3% carbon...Ch. 18 - Prob. 18.26DQCh. 18 - Ice is slippery to walk on, and especially...Ch. 18 - Hydrothermal vents are openings in the ocean floor...Ch. 18 - The dark areas on the moons surface are called...Ch. 18 - In addition to the normal cooking directions...Ch. 18 - A 20.0-L tank contains 4.86 104 kg of helium at...Ch. 18 - Helium gas with a volume of 3.20 L, under a...Ch. 18 - A cylindrical tank has a tight-fitting piston that...Ch. 18 - A 3.00-L lank contains air at 3.00 atm and 20.0C....Ch. 18 - Planetary Atmospheres. (a) Calculate the density...Ch. 18 - You have several identical balloons. You...Ch. 18 - A Jaguar XK8 convertible has an eight-cylinder...Ch. 18 - A welder using a tank of volume 0.0750 m3 fills it...Ch. 18 - A large cylindrical tank contains 0.750 m3 of...Ch. 18 - An empty cylindrical canister 1.50 m long and 90.0...Ch. 18 - The gas inside a balloon will always have a...Ch. 18 - An ideal gas has a density of 1.33 106 g/cm3 at...Ch. 18 - If a certain amount of ideal gas occupies a volume...Ch. 18 - A diver observes a bubble of air rising from the...Ch. 18 - A metal tank with volume 3.10 L will burst if the...Ch. 18 - Three moles of an ideal gas are in a rigid cubical...Ch. 18 - With the assumptions of Example 18.4 (Section...Ch. 18 - With the assumption that the air temperature is a...Ch. 18 - (a) Calculate the mass of nitrogen present in a...Ch. 18 - At an altitude of 11,000 m (a typical cruising...Ch. 18 - Prob. 18.21ECh. 18 - Prob. 18.22ECh. 18 - Modern vacuum pumps make it easy to attain...Ch. 18 - The Lagoon Nebula (Fig. E18.24) is a cloud of...Ch. 18 - In a gas at standard conditions, what is the...Ch. 18 - How Close Together Are Gas Molecules? Consider an...Ch. 18 - (a) What is the total translational kinetic energy...Ch. 18 - A flask contains a mixture of neon (Ne), krypton...Ch. 18 - We have two equal-size boxes, A and B. Each box...Ch. 18 - A container with volume 1.64 L is initially...Ch. 18 - Prob. 18.31ECh. 18 - Martian Climate. The atmosphere of Mars is mostly...Ch. 18 - Prob. 18.33ECh. 18 - Calculate the mean free path of air molecules at...Ch. 18 - At what temperature is the root-mean-square speed...Ch. 18 - Prob. 18.36ECh. 18 - Prob. 18.37ECh. 18 - Perfectly rigid containers each hold n moles of...Ch. 18 - (a) Compute the specific heat at constant volume...Ch. 18 - Prob. 18.40ECh. 18 - Prob. 18.41ECh. 18 - For a gas of nitrogen molecules (N2), what must...Ch. 18 - Prob. 18.43ECh. 18 - Meteorology. The vapor pressure is the pressure of...Ch. 18 - Calculate the volume of 1.00 mol of liquid water...Ch. 18 - A physics lecture room at 1.00 atm and 27.0C has a...Ch. 18 - CP BIO The Effect of Altitude on the Lungs. (a)...Ch. 18 - CP BIO The Bends. If deep-sea divers rise to the...Ch. 18 - CP A hot-air balloon stays aloft because hot air...Ch. 18 - In an evacuated enclosure, a vertical cylindrical...Ch. 18 - A cylinder 1.00 m tall with inside diameter 0.120...Ch. 18 - CP During a test dive in 1939, prior to being...Ch. 18 - Atmosphere or Titan. Titan, the largest satellite...Ch. 18 - Pressure on Venus. At the surface of Venus the...Ch. 18 - An automobile tire has a volume of 0.0150 m3 on a...Ch. 18 - A flask with a volume of 1.50 L, provided with a...Ch. 18 - CP A balloon of volume 750 m3 is to be filled with...Ch. 18 - A vertical cylindrical tank contains 1.80 mol of...Ch. 18 - CP A large tank of water has a hose connected to...Ch. 18 - CP A light, plastic sphere with mass m = 9.00 g...Ch. 18 - Prob. 18.61PCh. 18 - BIO A person at rest inhales 0.50 L of air with...Ch. 18 - You have two identical containers, one containing...Ch. 18 - The size of an oxygen molecule is about 2.0 1010...Ch. 18 - A sealed box contains a monatomic ideal gas. The...Ch. 18 - Helium gas is in a cylinder that has rigid walls....Ch. 18 - You blow up a spherical balloon to a diameter of...Ch. 18 - CP (a) Compute the increase in gravitational...Ch. 18 - Prob. 18.69PCh. 18 - Prob. 18.70PCh. 18 - It is possible to make crystalline solids that are...Ch. 18 - Hydrogen on the Sun. The surface of the sun has a...Ch. 18 - Prob. 18.73PCh. 18 - Planetary Atmospheres. (a) The temperature near...Ch. 18 - Prob. 18.75PCh. 18 - Prob. 18.76PCh. 18 - CALC (a) Explain why in a gas of N molecules, the...Ch. 18 - Prob. 18.78PCh. 18 - CP Oscillations of a Piston. A vertical cylinder...Ch. 18 - Prob. 18.80PCh. 18 - DATA The Dew Point and Clouds. The vapor pressure...Ch. 18 - DATA The statistical quantities average value and...Ch. 18 - CP Dark Nebulae and the Interstellar Medium. The...Ch. 18 - CALC Earths Atmosphere. In t he troposphere, the...Ch. 18 - Prob. 18.85PPCh. 18 - Estimate the ratio of the thermal conductivity of...Ch. 18 - The rate of effusionthat is, leakage of a gas...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, physics and related others by exploring similar questions and additional content below.Similar questions
- In solid KCI the smallest distance between the centers of a. potassium ion and a chloride ion is 314 pm. Calculate the length of the edge of the unit cell and the density of KCI, assuming it has the same structure as sodium chloride.arrow_forward1. A model for the potential energy interaction between the two nitrogen atoms in the N2 molecule is proposed that has the form: v(4) = 4E, (4)* - ()'] 12 a. Find the position of the potential minimum and its value there, in terms of o and Eo, respectively. What do these parameters represent physically about the molecule? b. Draw a hand sketch of V(r) showing rmin, V(rmin) and where V crosses the r axis. c. If the atom is disturbed from its equilibrium by a small amount, show that the 7.56. frequency of oscillation is w = d. For molecular nitrogen, the bond length is 1.1 x 10-1°m, the bond (binding) energy is 9.79 eV (15.66 x 10-19 J), the mass is 14 amu = 23.38 x 10-27 kg. In the spectroscopy laboratory, this vibration is measured to be 8.8 x 1013 Hz. Is this a good model for the interatomic potential? (Recall o = 2n times frequency in Hz) where m is the mass of a nitrogen atom.arrow_forward(a): Calculate Miller's indices in the hexagonal structure of its intersections. ai = 1, ar--1/2, as = 1,c= o and draw it. (b): the potential energy of a diatomic molecule is given by U = A B . where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV. m2 and B = 1.488 x 10 eV.m. Find the separation distance at which the energy of the molecule is a minimum. Q3: Calculate the dhai of tetragonal using the concepts of reciprocal latticearrow_forward
- Let E = 2{[(x + 1)^2][(y + 2)^2][(z + 3)^3]} V in free space. At P(2,-1,4) find pv. -15.67 nC/m^3 -16.67 nC/m^3 -17.67 nC/m^3 -18.67 nC/m^3arrow_forwardAn isolated LiCl molecule has its chloride ion (mass = 35 u) at x= 0 pm , and its lithium ion (7 u) at x = 202 pm. Where is the LiCl molecule's mass centered? 40.4 pm O 101 pm O o pm O +33.7 pm O 202 pm cannot determine with the information givenarrow_forwardNO.54arrow_forward
- N 2 has a molecular weight of 28.02 g/mol a bit larger than that of a Ne atom, 20.18 g/mol. (a) At a particular temperature, Z trans= 1.90 x 10 26 for Ne in a specific container. What is the translational partition function for a N2 molecule in this container at the same temperature? (b) At 100 K, the rotational partition function for N2is found to be 17.39. What would you expect it to be at 500 K?arrow_forwardQuestion 6: Free energy minimization Consider a theoretical system in which the particles interact so that the internal energy depends on volume as U = nRT + n², where A = 1.31e+01 J m³/mole² is a very small repulsive interaction between the particles and S = nRln V. Using minimization of free energy with respect to the volume, find the external pressure if the equilibrium volume is 1.64e-02 m³, the number of particles is 3.04e+00 moles, and the temperature is 2.30e+02 K (a) 3.55e+05 Pa (b) -9.54e+04 Pa (c) 3.62e+05 Pa (d) 3.48e+05 Pa (e) 8.05e+05 Pa ✓ ✓ 100% This question is complete and cannot be answered again.arrow_forwardCalculate the molecular translational partition functions in a volume of 1 cm at 298°K for the hydrogen molecule: H2 6.134 x 1025 O 6.175 x 1024 O 1.118 x 1023 O 1.173 x 1025 2.750 x 1024arrow_forward
- Hcp structure . Show that the c/a ratio for an ideal hexagonal close- packed structure is (8/3)^1/2 = 1.633 . if c/a is significantly larger than this value , the crystal structure may be thought of as composed of planes of closely packed atoms, the planes being loosely stacked.arrow_forwardMost of the mass of an atom is in its nucleus. Model the mass distribution in a diatomic molecule as two spheres of uniform density, each of radius 2.00 x 10-15 m and mass 1.00 x 10-26 kg, located at points along the y axis as in 42.5a, and separated by 2.00 x 10-10 m. Rotation about the axis joining the nuclei in the diatomic molecule is ordinarily ignored because the first excited state would have an energy that is too high to access. To see why, calculate the ratio of the energy of the first excited state for rotation about the y axis to the energy of the first excited state for rotation about the x axis.arrow_forwardA molecule in a gas undergoes about 1.0 × 109 collisions in each second. Suppose that (i) every collision is effective in deactivating the molecule rotationally and (ii) that one collision in 10 is effective. Calculate the width (in hertz) of rotational transitions in the molecule.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physics for Scientists and Engineers with Modern ...PhysicsISBN:9781337553292Author:Raymond A. Serway, John W. JewettPublisher:Cengage LearningModern PhysicsPhysicsISBN:9781111794378Author:Raymond A. Serway, Clement J. Moses, Curt A. MoyerPublisher:Cengage Learning
Physics for Scientists and Engineers with Modern ...
Physics
ISBN:9781337553292
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning
Modern Physics
Physics
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Cengage Learning